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Almonds, pottery, wood help date famed Kyrenia shipwreck

Historic shipwrecks often evoke dreams of sunken riches waiting on the bottom of the ocean to be reclaimed.
The almonds, combined with newly cleaned wood samples and the team’s modeling and radiocarbon-dating expertise, led the Cornell Tree-Ring Laboratory to identify the likeliest timeline of the Kyrenia’s sinking as between 296-271 BCE, with a strong probability it occurred between 286-272 BCE.
The team’s paper, “A Revised Radiocarbon Calibration Curve 350-250 BCE Impacts High-Precision Dating of the Kyrenia Ship,” will publish June 26 at 2 pm ET in PLoS ONE. The lead author is Sturt Manning, Distinguished Professor of Arts and Sciences in Classical Archaeology in the College of Arts and Sciences.
The Kyrenia has a storied legacy as the first major Greek Hellenistic-period ship to be found, in 1965, with a largely intact hull. From 1967-69, it was excavated along with its cargo, which included hundreds of ceramic vessels, then reassembled offsite and scientifically studied.
“Kyrenia was one of the first times it was realized this type of rich evidence from the classical world could be found largely intact more than 2,000 years later on the seabed, if you could find it,” said Sturt Manning. “It was a bit of a landmark moment, the idea that you actually could dive, excavate and bring up a classical-era ship and so discover this long-past world directly. Shipwrecks are unique time capsules, and you can get amazing preservation.”
For the last six decades, the Kyrenia has provided archeologists and historians with key insights into the development of ancient ship technology, construction practices and maritime trade. To date, no fewer than three Kyrenia replicas have been produced and launched, and these reconstructions have yielded considerable information on ancient ships and their sailing performance. However, the timeline of the Kyrenia’s provenance and the exact date of its sinking has always been vague at best. The initial efforts to date the ship were based on its recovered artifacts, such as the pottery on board and a small batch of coins, which initially led researchers to estimate the ship was built and sank in the later 300s BCE.
“Classical texts and finds at port sites already told us this era was significant for widespread maritime trade and connections all around the Mediterranean — an early period of globalization,” Manning said. “But the discovery of the Kyrenia ship, just under 15 meters long, likely with a crew of four, dramatically made this all very immediate and real. It yielded key insights into the practicalities of the earlier part of a millennium of intense maritime activity in the Mediterranean, from Greek through Late Antique times.”
The first volume of the final publication of the Kyrenia ship project, released last year, argued the wrecking date was a little later, closer to 294-290 BCE, but the primary piece of evidence — a poorly preserved, nearly illegible coin — was not watertight.
Manning’s team, which included co-authors Madeleine Wenger ’24 and Brita Lorentzen, ’06, Ph.D. ’15, sought to secure a date.
The perils of polyethylene glycol
The biggest hurdle for accurately dating the Kyrenia has been another artifact, one from the 20th century: polyethylene glycol (PEG). Excavators and preservationists often applied the petroleum-based compound to waterlogged wood to prevent it from decomposing after it was lifted out of the ocean’s oxygen-free environment.
“PEG was a standard treatment for decades. The trouble is it’s a petroleum product,” Manning said, “which means that if you’ve got PEG in the wood, you have this contamination from ancient fossil carbon that makes radiocarbon dating impossible.”
Manning’s team worked with researchers at the University of Groningen in the Netherlands to develop a new method to clean PEG out of wood, and they demonstrated it on PEG-treated Roman-era samples from Colchester, England, that already had established dendrochronological (tree-ring sequence) dates.
“We removed the PEG from the wood, we radiocarbon dated it and we showed that in each case, we got a radiocarbon age consistent with the real (known) age,” Manning said. “We basically got 99.9% of the PEG removed.”
They used that technique to remove PEG from a Kyrenia sample that Manning and collaborators had tried, and failed, to accurately date 10 years ago. The team also now dated a tiny, twisted piece of wood that was salvaged from the Kyrenia in the late 1960s but was too small to be included in the reconstruction, thus avoiding PEG-treatment. It subsequently sat in a jar of water in a museum for 50-odd years.
The dates showed that the most recent preserved tree-rings from these timbers grew in the mid-later 4th century BCE. Because the samples did not include bark, the researchers couldn’t determine the exact date the original trees were felled, but could say the date was likely after approximately 355-291 BCE.
Organic evidence
Working with the Kyrenia’s original excavation team, the researchers examined its various artifacts, including the pottery and coins, with a focus on organic materials, including an astragalus (a sheep or goat ankle bone once used for games and divining rituals in several ancient cultures) and thousands of fresh green almonds found in some of the large amphorae, i.e., ceramic jars. These “short-lived” sample materials helped define the date of the ship’s last voyage.
The team applied combined statistical modeling with the dendrochronology of the wood samples to get a level of dating that was much more precise than previous efforts. The modeling identified the most likely range of dates for the final voyage to be between 305-271 BCE (95.4% probability) and 286-272 BCE (68.3% probability) — several years more recent than current estimations.
But there was one big hiccup along the way. The new dates didn’t align with the international radiocarbon calibration curve, which is based on known-age tree-rings and is used to convert radiocarbon measurements into calendar dates for the northern hemisphere.
Manning took a closer look at data behind the calibration curve, which has been assembled over many decades by dozens of labs and hundreds of scientists. He discovered that the period between 350 and 250 BCE had no modern accelerator mass spectrometry (AMS) radiocarbon data behind it. Instead, the calibration curve in this period relied on only a few measurements conducted in the 1980s and 1990s using an older type of radiocarbon-dating technology. With collaborators in the U.S. and the Netherlands, the team measured known-age single-year sequoia and oak samples to re-calibrate the curve for the period 433-250 BCE. That not only helped clarify a big spike in radiocarbon production caused by a minimum of solar activity centered around 360 BCE, but also led to important revisions to the curve in the period around 300 BCE — improvements that were critical to dating the Kyrenia.
Manning anticipates the new findings will not only clarify the timeline of the Kyrenia and its cargo but will also help researchers using the calibration curve for very different projects.
“This revised curve 400-250 BCE now has relevance to other problems that researchers are working on whether in Europe or China or somewhere else in the northern hemisphere,” he said. “Half of the people who cite the paper in the future will be citing the fact that we’ve revised the radiocarbon calibration curve in this period, and only half will be saying the Kyrenia shipwreck is really important and has a much better date.”
Co-authors include researchers from the Oxford Dendrochronology Laboratory, the University of Groningen and the University of California, Irvine.
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Early dark energy could resolve cosmology’s two biggest puzzles

A new study by MIT physicists proposes that a mysterious force known as early dark energy could solve two of the biggest puzzles in cosmology and fill in some major gaps in our understanding of how the early universe evolved.
Now, the MIT team has found that both puzzles could be resolved if the early universe had one extra, fleeting ingredient: early dark energy. Dark energy is an unknown form of energy that physicists suspect is driving the expansion of the universe today. Early dark energy is a similar, hypothetical phenomenon that may have made only a brief appearance, influencing the expansion of the universe in its first moments before disappearing entirely.
Some physicists have suspected that early dark energy could be the key to solving the Hubble tension, as the mysterious force could accelerate the early expansion of the universe by an amount that would resolve the measurement mismatch.
The MIT researchers have now found that early dark energy could also explain the baffling number of bright galaxies that astronomers have observed in the early universe. In their new study, reported in the Monthly Notices of the Royal Astronomical Society, the team modeled the formation of galaxies in the universe’s first few hundred million years. When they incorporated a dark energy component only in that earliest sliver of time, they found the number of galaxies that arose from the primordial environment bloomed to fit astronomers’ observations.
“You have these two looming open-ended puzzles,” says study co-author Rohan Naidu, a postdoc in MIT’s Kavli Institute for Astrophysics and Space Research. “We find that in fact, early dark energy is a very elegant and sparse solution to two of the most pressing problems in cosmology.”
The study’s co-authors include lead author and Kavli postdoc Xuejian (Jacob) Shen, and MIT professor of physics Mark Vogelsberger, along with Michael Boylan-Kolchin at the University of Texas at Austin, and Sandro Tacchella at the University of Cambridge.
Big city lights
Based on standard cosmological and galaxy formation models, the universe should have taken its time spinning up the first galaxies. It would have taken billions of years for primordial gas to coalesce into galaxies as large and bright as the Milky Way.
But in 2023, NASA’s James Webb Space Telescope (JWST) made a startling observation. With an ability to peer farther back in time than any observatory to date, the telescope uncovered a surprising number of bright galaxies as large as the modern Milky Way within the first 500 million years, when the universe was just 3 percent of its current age.
“The bright galaxies that JWST saw would be like seeing a clustering of lights around big cities, whereas theory predicts something like the light around more rural settings like Yellowstone National Park,” Shen says. “And we don’t expect that clustering of light so early on.”
For physicists, the observations imply that there is either something fundamentally wrong with the physics underlying the models or a missing ingredient in the early universe that scientists have not accounted for. The MIT team explored the possibility of the latter, and whether the missing ingredient might be early dark energy.
Physicists have proposed that early dark energy is a sort of antigravitational force that is turned on only at very early times. This force would counteract gravity’s inward pull and accelerate the early expansion of the universe, in a way that would resolve the mismatch in measurements. Early dark energy, therefore, is considered the most likely solution to the Hubble tension.
Galaxy skeleton
The MIT team explored whether early dark energy could also be the key to explaining the unexpected population of large, bright galaxies detected by JWST. In their new study, the physicists considered how early dark energy might affect the early structure of the universe that gave rise to the first galaxies. They focused on the formation of dark matter halos — regions of space where gravity happens to be stronger, and where matter begins to accumulate.
“We believe that dark matter halos are the invisible skeleton of the universe,” Shen explains. “Dark matter structures form first, and then galaxies form within these structures. So, we expect the number of bright galaxies should be proportional to the number of big dark matter halos.”
The team developed an empirical framework for early galaxy formation, which predicts the number, luminosity, and size of galaxies that should form in the early universe, given some measures of “cosmological parameters.” Cosmological parameters are the basic ingredients, or mathematical terms, that describe the evolution of the universe.
Physicists have determined that there are at least six main cosmological parameters, one of which is the Hubble constant — a term that describes the universe’s rate of expansion. Other parameters describe density fluctuations in the primordial soup, immediately after the Big Bang, from which dark matter halos eventually form.
The MIT team reasoned that if early dark energy affects the universe’s early expansion rate, in a way that resolves the Hubble tension, then it could affect the balance of the other cosmological parameters, in a way that might increase the number of bright galaxies that appear at early times. To test their theory, they incorporated a model of early dark energy (the same one that happens to resolve the Hubble tension) into an empirical galaxy formation framework to see how the earliest dark matter structures evolve and give rise to the first galaxies.
“What we show is, the skeletal structure of the early universe is altered in a subtle way where the amplitude of fluctuations goes up, and you get bigger halos, and brighter galaxies that are in place at earlier times, more so than in our more vanilla models,” Naidu says. “It means things were more abundant, and more clustered in the early universe.”
“A priori, I would not have expected the abundance of JWST’s early bright galaxies to have anything to do with early dark energy, but their observation that EDE pushes cosmological parameters in a direction that boosts the early-galaxy abundance is interesting,” says Marc Kamionkowski, professor of theoretical physics at Johns Hopkins University, who was not involved with the study. “I think more work will need to be done to establish a link between early galaxies and EDE, but regardless of how things turn out, it’s a clever — and hopefully ultimately fruitful — thing to try.”
“We demonstrated the potential of early dark energy as a unified solution to the two major issues faced by cosmology. This might be an evidence for its existence if the observational findings of JWST get further consolidated,” Vogelsberger concludes. “In the future, we can incorporate this into large cosmological simulations to see what detailed predictions we get.”
This research was supported, in part, by NASA and the National Science Foundation.
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Plant-derived secondary organic aerosols can act as mediators of plant-plant interactions

A new study published in Science reveals that plant-derived secondary organic aerosols (SOAs) can act as mediators of plant-plant interactions. This research was conducted through the cooperation of chemical ecologists, plant ecophysiologists and atmospheric physicists at the University of Eastern Finland.
The study showed that Scots pine seedlings, when damaged by large pine weevils, release VOCs that activate defences in nearby plants of the same species. Interestingly, the biological activity persisted after VOCs were oxidized to form SOAs. The results indicated that the elemental composition and quantity of SOAs likely determines their biological functions.
“A key novelty of the study is the finding that plants adopt subtly different defence strategies when receiving signals as VOCs or as SOAs, yet they exhibit similar degrees of resistance to herbivore feeding,” said Professor James Blande, head of the Environmental Ecology Research Group. This observation opens up the possibility that plants have sophisticated sensing systems that enable them to tailor their defences to information derived from different types of chemical cue.
“Considering the formation rate of SOAs from their precursor VOCs, their longer lifetime compared to VOCs, and the atmospheric air mass transport, we expect that the ecologically effective distance for interactions mediated by SOAs is longer than that for plant interactions mediated by VOCs,” said Professor Annele Virtanen, head of the Aerosol Physics Research Group. This could be interpreted as plants being able to detect cues representing close versus distant threats from herbivores.
The study is expected to open up a whole new complex research area to environmental ecologists and their collaborators, which could lead to new insights on the chemical cues structuring interactions between plants.
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Folded or cut, this lithium-sulfur battery keeps going

Most rechargeable batteries that power portable devices, such as toys, handheld vacuums and e-bikes, use lithium-ion technology. But these batteries can have short lifetimes and may catch fire when damaged. To address stability and safety issues, researchers reporting in ACS Energy Letters have designed a lithium-sulfur (Li-S) battery that features an improved iron sulfide cathode. One prototype remains highly stable over 300 charge-discharge cycles, and another provides power even after being folded or cut.
The team coated iron sulfide cathodes in different polymers and found in initial electrochemical performance tests that polyacrylic acid (PAA) performed best, retaining the electrode’s discharge capacity after 300 charge-discharge cycles. Next, the researchers incorporated a PAA-coated iron sulfide cathode into a prototype battery design, which also included a carbonate-based electrolyte, a lithium metal foil as an ion source, and a graphite-based anode. They produced and then tested both pouch cell and coin cell battery prototypes.
After more than 100 charge-discharge cycles, Wang and colleagues observed no substantial capacity decay in the pouch cell. Additional experiments showed that the pouch cell still worked after being folded and cut in half. The coin cell retained 72% of its capacity after 300 charge-discharge cycles. They next applied the polymer coating to cathodes made from other metals, creating lithium-molybdenum and lithium-vanadium batteries. These cells also had stable capacity over 300 charge-discharge cycles. Overall, the results indicate that coated cathodes could produce not only safer Li-S batteries with long lifespans, but also efficient batteries with other metal sulfides, according to Wang’s team.
The authors acknowledge funding from the National Natural Science Foundation of China; the Natural Science Foundation of Sichuan, China; and the Beijing National Laboratory for Condensed Matter Physics.
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