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ITMO researchers create nanoparticle paste to make perovskite solar cells more efficient

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ITMO researchers create nanoparticle paste to make perovskite solar cells more efficient

Researchers from ITMO’s School of Physics and Engineering have created a paste of titanium dioxide and resonant silicon nanoparticles that will increase the generation of photocurrent in perovskite solar cells and maximize their efficiency. The results of the work were described in a paper published in Nano Energy.

The efficiency of halide perovskite solar cells is over 25%, which together with their low cost makes them one of the most promising devices in modern photovoltaics. One of two strategies can be used to further boost their efficiency: improving the charge collection or increasing light absorption by the charge generating layer. The first strategy also means the need to introduce other substances or 2D structures into perovskites, which makes the resulting devices more expensive.

Researchers from ITMO University together with colleagues from Tor Vergata University went around this problem by using Mie-resonant silicon nanoparticles, as silicon is one of the elements most accessible in nature. They used colloid chemistry methods to create a silicon-based nanoparticle paste to precisely control the light scattering inside a perovskite solar cell. This solution made it possible to increase the generation of photo-induced current in the perovskite structure and reach the efficiency maximum of solar cells based on the simplest perovskite composition.

“We have improved the titanium paste that is needed to selectively collect electrons in perovskite cells. We add resonant nanoparticles to the electron transport paste in a chosen concentration in the process of solar cells’ production. This way, the preparation process doesn’t get more complicated – and it helps that silicon particles are cheap, too,” explains Aleksandra Furasova, first author of the paper and a junior research associate at ITMO’s School of Physics and Engineering.

“We have also analyzed the effect of the spatial location of the nanoparticles on the direction of light propagation and changed their concentration in the paste, so that all the incident light is focused on the perovskite.

This directly affects the efficiency of converting light into electricity, as well as all main photovoltaic parameters. Using multi-physical calculations, we identified the optimal nanoparticle concentration and developed an ideal paste to create the electron transport layer that helped us reach nearly maximal efficiency for this type of solar cell.”

According to the researchers, it was important to optimize the spatial location of silicon nanoparticles in the considered devices. In order to do so, they provided numerical calculations that accounted for electrophysical and optical properties of all layers and nanoparticles when they are subjected to external radiation and voltage.

These calculations allowed them to determine how the size of and distance between resonant nanoparticles affects the optical and electrophysical properties of the whole structure.

The suggested method is simple, accessible, universally applicable, and doesn’t significantly increase the production costs of solar cells.

“In this project, we applied the spin coating method, meaning that we get thin homogeneous films as liquids deposit on the flat substrates, but other methods can also be used to scale the technology. The resulting paste is a multipurpose product that can be used in production of other kinds of perovskite solar cells, as well as for photodetectors and other perovskite-based optoelectronic devices. We believe that this solution will be in demand,” comments Sergey Makarov, professor at ITMO’s School of Physics and Engineering.

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Innovative approach to perovskite solar cells achieves 24.5% efficiency

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Innovative approach to perovskite solar cells achieves 24.5% efficiency


Innovative approach to perovskite solar cells achieves 24.5% efficiency

by Simon Mansfield

Sydney, Australia (SPX) Mar 28, 2024






In groundbreaking research published in Nano Energy, a team led by Prof. CHEN Chong at the Hefei Institutes of Physical Science, part of the Chinese Academy of Sciences, has significantly improved the performance of perovskite solar cells (PSCs). By integrating inorganic nano-material tin sulfoxide (SnSO) as a dopant, they have boosted the photoelectric conversion efficiency (PCE) of PSCs to an impressive 24.5%.

Traditional methods of enhancing the charge transport in the critical hole transport layer (HTL) of PSCs involve the use of lithium trifluoromethanesulfonyl imide (Li-TFSI) to facilitate the oxidation of the HTL material spiro-OMeTAD. However, this method suffers from low doping efficiency and can leave excess Li-TFSI in the spiro-OMeTAD film, reducing its compactness and long-term conductivity. Additionally, the oxidation process typically requires 10-24 hours to achieve the desired electrical conductivity and work function.



The HFIPS team’s innovation lies in their development of a rapid and replicable method to control the oxidation of nanomaterials, using SnSO nanomaterial to pre-oxidize spiro-OMeTAD in precursor solutions. This novel approach not only enhances conductivity but also optimizes the energy level position of the HTL, culminating in a high PCE of 24.5%.



One of the key advantages of the SnSO-regulated spiro-OMeTAD HTL is its pinhole-free, uniform, and smooth morphology, which maintains its performance and physical integrity even under challenging conditions of high temperature and humidity. Additionally, the oxidation process facilitated by this method is significantly faster, taking only a few hours- a crucial factor in improving the commercial production efficiency of PSCs.



Prof. CHEN Chong highlighted the importance of this breakthrough, stating, “Also, the oxidation process only takes a few hours, which is good for improving the commercial preparation efficiency of PSCs.” This advancement not only marks a significant leap in the efficiency and stability of PSCs but also holds substantial implications for their commercial viability.



Research Report:A nanomaterial-regulated oxidation of hole transporting layer for highly stable and efficient perovskite solar cells


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Revolutionary technique boosts flexible solar cell efficiency to record high

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Revolutionary technique boosts flexible solar cell efficiency to record high


Revolutionary technique boosts flexible solar cell efficiency to record high

by Simon Mansfield

Sydney, Australia (SPX) Mar 28, 2024






Researchers at Tsinghua University have made a significant breakthrough in the efficiency of flexible solar cells, leveraging a novel fabrication technique to set a new efficiency record. This advancement addresses the longstanding challenge of the lower energy conversion efficiency in flexible solar cells compared to their rigid counterparts, offering promising implications for aerospace and flexible electronics applications.

Flexible perovskite solar cells (FPSCs), despite their potential, have historically lagged in efficiency due to the polyethylene terephthalate (PET)-based flexible substrate’s inherent softness and inhomogeneity. This limitation, coupled with durability issues arising from the substrate’s susceptibility to water and oxygen infiltration, has hindered the practical deployment of FPSCs.



The team from the State Key Laboratory of Power System Operation and Control at Tsinghua University, alongside collaborators from the Center for Excellence in Nanoscience at the National Center for Nanoscience and Technology in Beijing, introduced a chemical bath deposition (CBD) technique. This method facilitates the deposition of tin oxide (SnO2) on flexible substrates without the need for strong acids, which are detrimental to such substrates. Tin oxide is essential for the FPSCs as it acts as an electron transport layer, crucial for the cells’ power conversion efficiency.



Associate Professor Chenyi Yi, a senior author of the study, explained, “Our method utilizes SnSO4 tin sulfate instead of SnCl2 tin chloride, making it suitable for acid-sensitive flexible substrates. This approach not only enhances the efficiency of FPSCs but also their durability, with a new power conversion efficiency benchmark set at 25.09%, certified at 24.90%.”



The novel fabrication technique also contributes to the FPSCs’ stability, as demonstrated by the cells maintaining 90% of their initial efficiency after being bent 10,000 times. The researchers noted an improved high-temperature stability in SnSO4-based FPSCs over those made with SnCl2, pointing towards the dual benefits of efficiency and durability enhancements.



The research signifies a leap towards industrial-scale production of high-efficiency FPSCs, with potential applications ranging from wearable technology and portable electronics to aerospace power sources and large-scale renewable energy solutions. The team’s findings, supported by Ningyu Ren, Liguo Tan, Minghao Li, Junjie Zhou, Yiran Ye, Boxin Jiao, and Liming Ding, mark a pivotal step in transitioning FPSCs from laboratory to commercial use.



Research Report:25% – Efficiency flexible perovskite solar cells via controllable growth of SnO2


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KAUST advances in perovskite-silicon tandem cells

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KAUST advances in perovskite-silicon tandem cells


KAUST advances in perovskite-silicon tandem cells

by Sophie Jenkins

London, UK (SPX) Mar 28, 2024






In 2009, researchers introduced perovskite-based solar cells, highlighting the potential of methylammonium lead bromide and methylammonium lead iodide-known as lead halide perovskites-for photovoltaic research. These materials, notable for their excellent light-absorbing properties, marked the beginning of an innovative direction in solar energy generation. Since then, the efficiency of perovskite solar cells has significantly increased, indicating a future where they are used alongside traditional silicon in solar panels.

Erkan Aydin, Stefaan De Wolf, and their team at King Abdullah University of Science and Technology (KAUST) have explored how this tandem technology could transition from experimental stages to commercial production. Perovskites are lauded for their low-temperature production process and their flexibility in application, offering a lighter, more adaptable, and potentially cost-effective alternative to silicon-based panels.



Combining perovskite with silicon in a single solar cell leverages the strengths of both materials, enhancing sunlight utilization and reducing losses that aren’t converted into electrical energy. “The synergy between perovskite and silicon technologies in tandem cells captures a broader spectrum of sunlight, minimizing energy loss and significantly boosting efficiency,” Aydin notes.



However, Aydin and his colleagues acknowledge challenges in scaling tandem solar-cell fabrication for the marketplace. For instance, the process of depositing perovskite on silicon surfaces is complicated by the silicon’s texture. Traditional laboratory methods like spin coating are not feasible for large-scale production due to their inefficiency and material wastage. Alternatives such as slot-die coating and physical vapor deposition present their own set of advantages and challenges.



Moreover, the durability of perovskite components under environmental stressors such as moisture, heat, and light remains a critical concern. Aydin emphasizes the need for focused research to enhance the reliability and lifespan of perovskite/silicon tandem cells, especially in harsh conditions.



Although tandem modules have already been demonstrated in proof-of-concept stages, the timeline for their market readiness is uncertain. Nonetheless, the successful development of efficient, commercial-grade perovskite/silicon solar cells is essential for meeting global energy demands sustainably.



Research Report:Pathways toward commercial perovskite/silicon tandem photovoltaics


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King Abdullah University of Science and Technology

All About Solar Energy at SolarDaily.com





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