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Mars habitability limited by its small size, isotope study suggests

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Mars habitability limited by its small size, isotope study suggests

Water is essential for life on Earth and other planets, and scientists have found ample evidence of water in Mars’ early history. But Mars has no liquid water on its surface today. New research from Washington University in St. Louis suggests a fundamental reason: Mars may be just too small to hold onto large amounts of water.

Remote sensing studies and analyses of Martian meteorites dating back to the 1980s posit that Mars was once water-rich, compared with Earth. NASA’s Viking orbiter spacecraft — and, more recently, the Curiosity and Perseverance rovers on the ground — returned dramatic images of Martian landscapes marked by river valleys and flood channels.

Despite this evidence, no liquid water remains on the surface. Researchers proposed many possible explanations, including a weakening of Mars’ magnetic field that could have resulted in the loss of a thick atmosphere.

But a study published the week of Sept. 20 in the Proceedings of the National Academy of Sciences suggests a more fundamental reason why today’s Mars looks so drastically different from the “blue marble” of Earth.

“Mars’ fate was decided from the beginning,” said Kun Wang, assistant professor of earth and planetary sciences in Arts & Sciences at Washington University, senior author of the study. “There is likely a threshold on the size requirements of rocky planets to retain enough water to enable habitability and plate tectonics, with mass exceeding that of Mars.”

For the new study, Wang and his collaborators used stable isotopes of the element potassium (K) to estimate the presence, distribution and abundance of volatile elements on different planetary bodies.


Potassium is a moderately volatile element, but the scientists decided to use it as a kind of tracer for more volatile elements and compounds, such as water. This is a relatively new method that diverges from previous attempts to use potassium-to-thorium (Th) ratios gathered by remote sensing and chemical analysis to determine the amount of volatiles Mars once had. In previous research, members of the research group used a potassium tracer method to study the formation of the moon.

Wang and his team measured the potassium isotope compositions of 20 previously confirmed Martian meteorites, selected to be representative of the bulk silicate composition of the red planet.

Using this approach, the researchers determined that Mars lost more potassium and other volatiles than Earth during its formation, but retained more of these volatiles than the moon and asteroid 4-Vesta, two much smaller and drier bodies than Earth and Mars.

The researchers found a well-defined correlation between body size and potassium isotopic composition.

“The reason for far lower abundances of volatile elements and their compounds in differentiated planets than in primitive undifferentiated meteorites has been a longstanding question,” said Katharina Lodders, research professor of earth and planetary sciences at Washington University, a coauthor of the study. “The finding of the correlation of K isotopic compositions with planet gravity is a novel discovery with important quantitative implications for when and how the differentiated planets received and lost their volatiles.”

“Martian meteorites are the only samples available to us to study the chemical makeup of the bulk Mars,” Wang said. “Those Martian meteorites have ages varying from several hundred millions to 4 billion years and recorded Mars’ volatile evolution history. Through measuring the isotopes of moderately volatile elements, such as potassium, we can infer the degree of volatile depletion of bulk planets and make comparisons between different solar system bodies.


“It’s indisputable that there used to be liquid water on the surface of Mars, but how much water in total Mars once had is hard to quantify through remote sensing and rover studies alone,” Wang said. “There are many models out there for the bulk water content of Mars. In some of them, early Mars was even wetter than the Earth. We don’t believe that was the case.”

Zhen Tian, a graduate student in Wang’s laboratory and a McDonnell International Academy Scholar, is first author of the paper. Postdoctoral research associate Piers Koefoed is a co-author, as is Hannah Bloom, who graduated from Washington University in 2020. Wang and Lodders are faculty fellows of the university’s McDonnell Center for the Space Sciences.

The findings have implications for the search for life on other planets besides Mars, the researchers noted.

Being too close to the sun (or, for exoplanets, being too close to their star) can affect the amount of volatiles that a planetary body can retain. This distance-from-star measurement is often factored into indexes of “habitable zones” around stars.

“This study emphasizes that there is a very limited size range for planets to have just enough but not too much water to develop a habitable surface environment,” said Klaus Mezger of the Center for Space and Habitability at the University of Bern, Switzerland, a co-author of the study. “These results will guide astronomers in their search for habitable exoplanets in other solar systems.”

Wang now thinks that, for planets that are within habitable zones, planetary size probably should be more emphasized and routinely considered when thinking about whether an exoplanet could support life.

“The size of an exoplanet is one of the parameters that is easiest to determine,” Wang said. “Based on size and mass, we now know whether an exoplanet is a candidate for life, because a first-order determining factor for volatile retention is size.”

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Early dark energy could resolve cosmology’s two biggest puzzles

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Mars habitability limited by its small size, isotope study suggests


A new study by MIT physicists proposes that a mysterious force known as early dark energy could solve two of the biggest puzzles in cosmology and fill in some major gaps in our understanding of how the early universe evolved.

One puzzle in question is the “Hubble tension,” which refers to a mismatch in measurements of how fast the universe is expanding. The other involves observations of numerous early, bright galaxies that existed at a time when the early universe should have been much less populated.

Now, the MIT team has found that both puzzles could be resolved if the early universe had one extra, fleeting ingredient: early dark energy. Dark energy is an unknown form of energy that physicists suspect is driving the expansion of the universe today. Early dark energy is a similar, hypothetical phenomenon that may have made only a brief appearance, influencing the expansion of the universe in its first moments before disappearing entirely.

Some physicists have suspected that early dark energy could be the key to solving the Hubble tension, as the mysterious force could accelerate the early expansion of the universe by an amount that would resolve the measurement mismatch.

The MIT researchers have now found that early dark energy could also explain the baffling number of bright galaxies that astronomers have observed in the early universe. In their new study, reported in the Monthly Notices of the Royal Astronomical Society, the team modeled the formation of galaxies in the universe’s first few hundred million years. When they incorporated a dark energy component only in that earliest sliver of time, they found the number of galaxies that arose from the primordial environment bloomed to fit astronomers’ observations.

You have these two looming open-ended puzzles,” says study co-author Rohan Naidu, a postdoc in MIT’s Kavli Institute for Astrophysics and Space Research. “We find that in fact, early dark energy is a very elegant and sparse solution to two of the most pressing problems in cosmology.”

The study’s co-authors include lead author and Kavli postdoc Xuejian (Jacob) Shen, and MIT professor of physics Mark Vogelsberger, along with Michael Boylan-Kolchin at the University of Texas at Austin, and Sandro Tacchella at the University of Cambridge.

Big city lights

Based on standard cosmological and galaxy formation models, the universe should have taken its time spinning up the first galaxies. It would have taken billions of years for primordial gas to coalesce into galaxies as large and bright as the Milky Way.

But in 2023, NASA’s James Webb Space Telescope (JWST) made a startling observation. With an ability to peer farther back in time than any observatory to date, the telescope uncovered a surprising number of bright galaxies as large as the modern Milky Way within the first 500 million years, when the universe was just 3 percent of its current age.

“The bright galaxies that JWST saw would be like seeing a clustering of lights around big cities, whereas theory predicts something like the light around more rural settings like Yellowstone National Park,” Shen says. “And we don’t expect that clustering of light so early on.”

For physicists, the observations imply that there is either something fundamentally wrong with the physics underlying the models or a missing ingredient in the early universe that scientists have not accounted for. The MIT team explored the possibility of the latter, and whether the missing ingredient might be early dark energy.

Physicists have proposed that early dark energy is a sort of antigravitational force that is turned on only at very early times. This force would counteract gravity’s inward pull and accelerate the early expansion of the universe, in a way that would resolve the mismatch in measurements. Early dark energy, therefore, is considered the most likely solution to the Hubble tension.

Galaxy skeleton

The MIT team explored whether early dark energy could also be the key to explaining the unexpected population of large, bright galaxies detected by JWST. In their new study, the physicists considered how early dark energy might affect the early structure of the universe that gave rise to the first galaxies. They focused on the formation of dark matter halos — regions of space where gravity happens to be stronger, and where matter begins to accumulate.

“We believe that dark matter halos are the invisible skeleton of the universe,” Shen explains. “Dark matter structures form first, and then galaxies form within these structures. So, we expect the number of bright galaxies should be proportional to the number of big dark matter halos.”

The team developed an empirical framework for early galaxy formation, which predicts the number, luminosity, and size of galaxies that should form in the early universe, given some measures of “cosmological parameters.” Cosmological parameters are the basic ingredients, or mathematical terms, that describe the evolution of the universe.

Physicists have determined that there are at least six main cosmological parameters, one of which is the Hubble constant — a term that describes the universe’s rate of expansion. Other parameters describe density fluctuations in the primordial soup, immediately after the Big Bang, from which dark matter halos eventually form.

The MIT team reasoned that if early dark energy affects the universe’s early expansion rate, in a way that resolves the Hubble tension, then it could affect the balance of the other cosmological parameters, in a way that might increase the number of bright galaxies that appear at early times. To test their theory, they incorporated a model of early dark energy (the same one that happens to resolve the Hubble tension) into an empirical galaxy formation framework to see how the earliest dark matter structures evolve and give rise to the first galaxies.

“What we show is, the skeletal structure of the early universe is altered in a subtle way where the amplitude of fluctuations goes up, and you get bigger halos, and brighter galaxies that are in place at earlier times, more so than in our more vanilla models,” Naidu says. “It means things were more abundant, and more clustered in the early universe.”

“A priori, I would not have expected the abundance of JWST’s early bright galaxies to have anything to do with early dark energy, but their observation that EDE pushes cosmological parameters in a direction that boosts the early-galaxy abundance is interesting,” says Marc Kamionkowski, professor of theoretical physics at Johns Hopkins University, who was not involved with the study. “I think more work will need to be done to establish a link between early galaxies and EDE, but regardless of how things turn out, it’s a clever — and hopefully ultimately fruitful — thing to try.”

We demonstrated the potential of early dark energy as a unified solution to the two major issues faced by cosmology. This might be an evidence for its existence if the observational findings of JWST get further consolidated,” Vogelsberger concludes. “In the future, we can incorporate this into large cosmological simulations to see what detailed predictions we get.”

This research was supported, in part, by NASA and the National Science Foundation.



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Plant-derived secondary organic aerosols can act as mediators of plant-plant interactions

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A new study published in Science reveals that plant-derived secondary organic aerosols (SOAs) can act as mediators of plant-plant interactions. This research was conducted through the cooperation of chemical ecologists, plant ecophysiologists and atmospheric physicists at the University of Eastern Finland.

It is well known that plants release volatile organic compounds (VOCs) into the atmosphere when damaged by herbivores. These VOCs play a crucial role in plant-plant interactions, whereby undamaged plants may detect warning signals from their damaged neighbours and prepare their defences. “Reactive plant VOCs undergo oxidative chemical reactions, resulting in the formation of secondary organic aerosols (SOAs). We wondered whether the ecological functions mediated by VOCs persist after they are oxidated to form SOAs,” said Dr. Hao Yu, formerly a PhD student at UEF, but now at the University of Bern.

The study showed that Scots pine seedlings, when damaged by large pine weevils, release VOCs that activate defences in nearby plants of the same species. Interestingly, the biological activity persisted after VOCs were oxidized to form SOAs. The results indicated that the elemental composition and quantity of SOAs likely determines their biological functions.

“A key novelty of the study is the finding that plants adopt subtly different defence strategies when receiving signals as VOCs or as SOAs, yet they exhibit similar degrees of resistance to herbivore feeding,” said Professor James Blande, head of the Environmental Ecology Research Group. This observation opens up the possibility that plants have sophisticated sensing systems that enable them to tailor their defences to information derived from different types of chemical cue.

“Considering the formation rate of SOAs from their precursor VOCs, their longer lifetime compared to VOCs, and the atmospheric air mass transport, we expect that the ecologically effective distance for interactions mediated by SOAs is longer than that for plant interactions mediated by VOCs,” said Professor Annele Virtanen, head of the Aerosol Physics Research Group. This could be interpreted as plants being able to detect cues representing close versus distant threats from herbivores.

The study is expected to open up a whole new complex research area to environmental ecologists and their collaborators, which could lead to new insights on the chemical cues structuring interactions between plants.



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Folded or cut, this lithium-sulfur battery keeps going

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Most rechargeable batteries that power portable devices, such as toys, handheld vacuums and e-bikes, use lithium-ion technology. But these batteries can have short lifetimes and may catch fire when damaged. To address stability and safety issues, researchers reporting in ACS Energy Letters have designed a lithium-sulfur (Li-S) battery that features an improved iron sulfide cathode. One prototype remains highly stable over 300 charge-discharge cycles, and another provides power even after being folded or cut.

Sulfur has been suggested as a material for lithium-ion batteries because of its low cost and potential to hold more energy than lithium-metal oxides and other materials used in traditional ion-based versions. To make Li-S batteries stable at high temperatures, researchers have previously proposed using a carbonate-based electrolyte to separate the two electrodes (an iron sulfide cathode and a lithium metal-containing anode). However, as the sulfide in the cathode dissolves into the electrolyte, it forms an impenetrable precipitate, causing the cell to quickly lose capacity. Liping Wang and colleagues wondered if they could add a layer between the cathode and electrolyte to reduce this corrosion without reducing functionality and rechargeability.

The team coated iron sulfide cathodes in different polymers and found in initial electrochemical performance tests that polyacrylic acid (PAA) performed best, retaining the electrode’s discharge capacity after 300 charge-discharge cycles. Next, the researchers incorporated a PAA-coated iron sulfide cathode into a prototype battery design, which also included a carbonate-based electrolyte, a lithium metal foil as an ion source, and a graphite-based anode. They produced and then tested both pouch cell and coin cell battery prototypes.

After more than 100 charge-discharge cycles, Wang and colleagues observed no substantial capacity decay in the pouch cell. Additional experiments showed that the pouch cell still worked after being folded and cut in half. The coin cell retained 72% of its capacity after 300 charge-discharge cycles. They next applied the polymer coating to cathodes made from other metals, creating lithium-molybdenum and lithium-vanadium batteries. These cells also had stable capacity over 300 charge-discharge cycles. Overall, the results indicate that coated cathodes could produce not only safer Li-S batteries with long lifespans, but also efficient batteries with other metal sulfides, according to Wang’s team.

The authors acknowledge funding from the National Natural Science Foundation of China; the Natural Science Foundation of Sichuan, China; and the Beijing National Laboratory for Condensed Matter Physics.



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