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6,000 years ago, men and women had equal access to resources
Using isotope geochemistry, a team from the University of Geneva (UNIGE) has uncovered new information about the Barmaz necropolis in Valais (Switzerland): 14% of the people buried 6,000 years ago at this site were not locals. What’s more, the study suggests that this Middle Neolithic agropastoral society — one of the oldest known in the western part of Switzerland — was relatively egalitarian. The isotope ratios of carbon, nitrogen and sulphur contained in the bones reveal that all members of the community, including people from elsewhere, had access to the same food resources. These results are published in the Journal of Archaeological Science: Reports.
The aim of the study carried out by Déborah Rosselet-Christ, a doctoral student at the Laboratory of Archaeology of Africa and Anthropolgy in the UNIGE Faculty of Science, is to apply isotope analysis to human remains dating from the Neolithic period to learn more about their diet and mobility. The levels of certain isotopes of carbon, nitrogen, sulphur and strontium depend on the environment in which each individual lives and eats. Isotopes are atoms that have the same number of electrons and protons but a different number of neutrons. This very precise and delicate technique is being applied for the first time to alpine agropastoral populations from the Middle Neolithic period in the western part of Switzerland.
Mobility according to the second molar
Excavated in the 1950s and 1990s, the Barmaz site at Collombey-Muraz in the Chablais region of Valais is one of the oldest remains of agropastoral societies in the western part of Switzerland to have preserved human remains. It comprises two necropolises containing the bones of around seventy individuals. For her master degree, Déborah Rosselet-Christ, the study’s first author, selected 49 of them (as many women as men) from whom she systematically took samples of collagen from certain bones, as well as fragments of enamel from their second molars.
”The second molar is a tooth whose crown forms between the ages of three and eight,” explains the researcher. ”Once formed, tooth enamel is not renewed for the rest of its life. Its chemical composition therefore reflects the environment in which its owner lived during childhood. Strontium (Sr) is a good marker of mobility. The ratio of abundance between two of its isotopes — i.e. their proportion — varies greatly depending on the age of the surrounding rocks. These chemical elements end up in the enamel via the food chain, leaving an indelible signature that is specific to each environment.”
Analysis of the strontium isotope ratios in the 49 individuals from Barmaz reveals a high degree of homogeneity in most of them and markedly different values in only 14% of the samples, indicating a different origin. ”The technique makes it possible to determine that these are individuals who did not live the first years of their lives in the place where they were buried, but it is more difficult to determine where they come from”, moderates Jocelyne Desideri, senior lecturer at the Laboratory of Archaeology of Africa and Anthropolgy in the UNIGE Faculty of Science, last author of the article. ”Our results show that people were on the move at that time. This comes as no surprise, as several studies have highlighted the same phenomenon in other places and at other times during the Neolithic period.”
Diet recorded in collagen
Collagen is used to determine the ratios of isotopes of carbon (δ13C), nitrogen (δ15N) and sulphur (δ34S). Each measurement provides information on specific aspects of the diet, such as the categories of plants according to the type of photosynthesis they use, the amount of animal protein or the intake of aquatic animals. As bones are constantly being renewed, the results only concern the last few years of an individual’s life. That said, the scientists were able to deduce that these former residents of the region of Barmaz had a diet based on terrestrial (rather than aquatic) resources, with a very high consumption of animal protein.
”What’s more interesting is that we didn’t measure any differences between men and women,” notes Déborah Rosselet-Christ. ”Nor even between locals and non-locals. These results therefore suggest equal access to food resources between the different members of the group, whatever their origin or sex. However, this is not always the case. There are, for example, dietary differences between the sexes in Neolithic populations in the south of France.”
A clearer picture of agropastoral societies
However, the scientists were able to show that non-local people were only buried in one of the necropolises (Barmaz I) and that higher levels of the nitrogen isotope were measured in the other (Barmaz II). Given that the two necropolises were contemporaneous (and only 150 metres apart), the latter observation raises the question of whether there was a difference in social status between the two groups of deceased.
”Our isotope measurements are an interesting complement to other approaches used in archaeology,” says Jocelyne Desideri. ”They help to clarify the picture we are trying to paint of the life of these early Alpine agropastoral societies, the relationships between individuals and their mobility.”
Déborah Rosselet-Christ is currently pursuing this work as part of her doctoral thesis, funded by the ALPproject of the Swiss National Science Foundation and co-directed by Jocelyne Desideri and Massimo Chiaradia (senior lecturer, Department of Earth sciences). Working alongside a multidisciplinary team specialising in genetics, palae-opathology, dental calculus and morphology, she is broadening her field of study by including other sites in Valais and the Val d’Aosta in Italy, covering a wider Neolithic period and using other isotopes, such as neodymium, which are potentially interesting in a prehistoric archaeological context.
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Early dark energy could resolve cosmology’s two biggest puzzles
A new study by MIT physicists proposes that a mysterious force known as early dark energy could solve two of the biggest puzzles in cosmology and fill in some major gaps in our understanding of how the early universe evolved.
Now, the MIT team has found that both puzzles could be resolved if the early universe had one extra, fleeting ingredient: early dark energy. Dark energy is an unknown form of energy that physicists suspect is driving the expansion of the universe today. Early dark energy is a similar, hypothetical phenomenon that may have made only a brief appearance, influencing the expansion of the universe in its first moments before disappearing entirely.
Some physicists have suspected that early dark energy could be the key to solving the Hubble tension, as the mysterious force could accelerate the early expansion of the universe by an amount that would resolve the measurement mismatch.
The MIT researchers have now found that early dark energy could also explain the baffling number of bright galaxies that astronomers have observed in the early universe. In their new study, reported in the Monthly Notices of the Royal Astronomical Society, the team modeled the formation of galaxies in the universe’s first few hundred million years. When they incorporated a dark energy component only in that earliest sliver of time, they found the number of galaxies that arose from the primordial environment bloomed to fit astronomers’ observations.
“You have these two looming open-ended puzzles,” says study co-author Rohan Naidu, a postdoc in MIT’s Kavli Institute for Astrophysics and Space Research. “We find that in fact, early dark energy is a very elegant and sparse solution to two of the most pressing problems in cosmology.”
The study’s co-authors include lead author and Kavli postdoc Xuejian (Jacob) Shen, and MIT professor of physics Mark Vogelsberger, along with Michael Boylan-Kolchin at the University of Texas at Austin, and Sandro Tacchella at the University of Cambridge.
Big city lights
Based on standard cosmological and galaxy formation models, the universe should have taken its time spinning up the first galaxies. It would have taken billions of years for primordial gas to coalesce into galaxies as large and bright as the Milky Way.
But in 2023, NASA’s James Webb Space Telescope (JWST) made a startling observation. With an ability to peer farther back in time than any observatory to date, the telescope uncovered a surprising number of bright galaxies as large as the modern Milky Way within the first 500 million years, when the universe was just 3 percent of its current age.
“The bright galaxies that JWST saw would be like seeing a clustering of lights around big cities, whereas theory predicts something like the light around more rural settings like Yellowstone National Park,” Shen says. “And we don’t expect that clustering of light so early on.”
For physicists, the observations imply that there is either something fundamentally wrong with the physics underlying the models or a missing ingredient in the early universe that scientists have not accounted for. The MIT team explored the possibility of the latter, and whether the missing ingredient might be early dark energy.
Physicists have proposed that early dark energy is a sort of antigravitational force that is turned on only at very early times. This force would counteract gravity’s inward pull and accelerate the early expansion of the universe, in a way that would resolve the mismatch in measurements. Early dark energy, therefore, is considered the most likely solution to the Hubble tension.
Galaxy skeleton
The MIT team explored whether early dark energy could also be the key to explaining the unexpected population of large, bright galaxies detected by JWST. In their new study, the physicists considered how early dark energy might affect the early structure of the universe that gave rise to the first galaxies. They focused on the formation of dark matter halos — regions of space where gravity happens to be stronger, and where matter begins to accumulate.
“We believe that dark matter halos are the invisible skeleton of the universe,” Shen explains. “Dark matter structures form first, and then galaxies form within these structures. So, we expect the number of bright galaxies should be proportional to the number of big dark matter halos.”
The team developed an empirical framework for early galaxy formation, which predicts the number, luminosity, and size of galaxies that should form in the early universe, given some measures of “cosmological parameters.” Cosmological parameters are the basic ingredients, or mathematical terms, that describe the evolution of the universe.
Physicists have determined that there are at least six main cosmological parameters, one of which is the Hubble constant — a term that describes the universe’s rate of expansion. Other parameters describe density fluctuations in the primordial soup, immediately after the Big Bang, from which dark matter halos eventually form.
The MIT team reasoned that if early dark energy affects the universe’s early expansion rate, in a way that resolves the Hubble tension, then it could affect the balance of the other cosmological parameters, in a way that might increase the number of bright galaxies that appear at early times. To test their theory, they incorporated a model of early dark energy (the same one that happens to resolve the Hubble tension) into an empirical galaxy formation framework to see how the earliest dark matter structures evolve and give rise to the first galaxies.
“What we show is, the skeletal structure of the early universe is altered in a subtle way where the amplitude of fluctuations goes up, and you get bigger halos, and brighter galaxies that are in place at earlier times, more so than in our more vanilla models,” Naidu says. “It means things were more abundant, and more clustered in the early universe.”
“A priori, I would not have expected the abundance of JWST’s early bright galaxies to have anything to do with early dark energy, but their observation that EDE pushes cosmological parameters in a direction that boosts the early-galaxy abundance is interesting,” says Marc Kamionkowski, professor of theoretical physics at Johns Hopkins University, who was not involved with the study. “I think more work will need to be done to establish a link between early galaxies and EDE, but regardless of how things turn out, it’s a clever — and hopefully ultimately fruitful — thing to try.”
“We demonstrated the potential of early dark energy as a unified solution to the two major issues faced by cosmology. This might be an evidence for its existence if the observational findings of JWST get further consolidated,” Vogelsberger concludes. “In the future, we can incorporate this into large cosmological simulations to see what detailed predictions we get.”
This research was supported, in part, by NASA and the National Science Foundation.
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Plant-derived secondary organic aerosols can act as mediators of plant-plant interactions
A new study published in Science reveals that plant-derived secondary organic aerosols (SOAs) can act as mediators of plant-plant interactions. This research was conducted through the cooperation of chemical ecologists, plant ecophysiologists and atmospheric physicists at the University of Eastern Finland.
The study showed that Scots pine seedlings, when damaged by large pine weevils, release VOCs that activate defences in nearby plants of the same species. Interestingly, the biological activity persisted after VOCs were oxidized to form SOAs. The results indicated that the elemental composition and quantity of SOAs likely determines their biological functions.
“A key novelty of the study is the finding that plants adopt subtly different defence strategies when receiving signals as VOCs or as SOAs, yet they exhibit similar degrees of resistance to herbivore feeding,” said Professor James Blande, head of the Environmental Ecology Research Group. This observation opens up the possibility that plants have sophisticated sensing systems that enable them to tailor their defences to information derived from different types of chemical cue.
“Considering the formation rate of SOAs from their precursor VOCs, their longer lifetime compared to VOCs, and the atmospheric air mass transport, we expect that the ecologically effective distance for interactions mediated by SOAs is longer than that for plant interactions mediated by VOCs,” said Professor Annele Virtanen, head of the Aerosol Physics Research Group. This could be interpreted as plants being able to detect cues representing close versus distant threats from herbivores.
The study is expected to open up a whole new complex research area to environmental ecologists and their collaborators, which could lead to new insights on the chemical cues structuring interactions between plants.
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Folded or cut, this lithium-sulfur battery keeps going
Most rechargeable batteries that power portable devices, such as toys, handheld vacuums and e-bikes, use lithium-ion technology. But these batteries can have short lifetimes and may catch fire when damaged. To address stability and safety issues, researchers reporting in ACS Energy Letters have designed a lithium-sulfur (Li-S) battery that features an improved iron sulfide cathode. One prototype remains highly stable over 300 charge-discharge cycles, and another provides power even after being folded or cut.
The team coated iron sulfide cathodes in different polymers and found in initial electrochemical performance tests that polyacrylic acid (PAA) performed best, retaining the electrode’s discharge capacity after 300 charge-discharge cycles. Next, the researchers incorporated a PAA-coated iron sulfide cathode into a prototype battery design, which also included a carbonate-based electrolyte, a lithium metal foil as an ion source, and a graphite-based anode. They produced and then tested both pouch cell and coin cell battery prototypes.
After more than 100 charge-discharge cycles, Wang and colleagues observed no substantial capacity decay in the pouch cell. Additional experiments showed that the pouch cell still worked after being folded and cut in half. The coin cell retained 72% of its capacity after 300 charge-discharge cycles. They next applied the polymer coating to cathodes made from other metals, creating lithium-molybdenum and lithium-vanadium batteries. These cells also had stable capacity over 300 charge-discharge cycles. Overall, the results indicate that coated cathodes could produce not only safer Li-S batteries with long lifespans, but also efficient batteries with other metal sulfides, according to Wang’s team.
The authors acknowledge funding from the National Natural Science Foundation of China; the Natural Science Foundation of Sichuan, China; and the Beijing National Laboratory for Condensed Matter Physics.
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