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A new dye shakes up solar cells

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A new dye shakes up solar cells

In 1991, scientists Brian O’Regan and Michael Gratzel at EPFL published a seminal paper describing a new type of solar cell: the dye-sensitized solar cell (DSSC), also known as “Gratzel cell”.

Simple and cheap to build while being flexible and versatile, DSSCs are already manufactured on a multi-megawatt scale, cutting a significant slice of the photovoltaic market, which currently supplies almost 3% of all the world’s electricity, well in the race to reduce carbon emissions.

Now, Dan Zhang and Marko Stojanovic, two PhD students in Gratzel’s lab at EPFL’s School of Basic Sciences, have led the development of a simple dye for DSSCs, called MS5. In devices, this new sensitizer can either be used as single dye, and produce an open-circuit voltage – the maximum voltage a solar cell can reach in full sunlight – of 1.24 Volts or as co-sensitizer, along with the commercial dye XY1b, and enable a power conversion efficiency of 13.5 %. Both are among the highest in the field of DSSCs.

The team used this new dye in combination with another organic sensitizer coded XY1b. Apart from absorbing photons from the blue and yellow domain of the solar emission, the role of the new dye in this tandem is to boost the voltage output of the device by retarding the recombination of charge carriers generated by light. Called MS5, the photosensitizer was used with a copper (II/I) electrolyte to enable the DSSC achieve its impressive efficiency.

“Our work constitutes an important breakthrough in the work of DSSCs and especially dye design,” says Michael Gratzel. “It shows that high performances are achievable with a relatively simple dye through judicious molecular engineering of the sensitizer’s molecular structure.”

Tested under ambient light conditions, the dye showed impressive performance, which is crucial for photovoltaics to be effective under cloudy conditions, or in-door applications to power electronic devices applied e.g. for the internet of things. And last but not least, MS5 is easy to synthesize up to the gram scale using a one-step procedure that researchers describe in their paper.

“Our results not only push the field of dye-sensitized solar cells further, but demonstrate EPFL’s leading expertise in the field,” says Marko Stojanovic.

The work is published in Nature Communications.

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The ZEUS Project to harness solar energy in space with nanowire technology

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The ZEUS Project to harness solar energy in space with nanowire technology


The ZEUS Project to harness solar energy in space with nanowire technology

by Hugo Ritmico

Madrid, Spain (SPXR) Oct 10, 2024






The University of Malaga (UMA) is collaborating in an international consortium to advance the collection and transmission of solar energy in space through the ‘ZEUS’ project, part of the Horizon EIC Pathfinder Challenges. This European project, coordinated by Lund University in Sweden, has been awarded nearly euro 4 million to develop innovative nanowire solar cells designed to operate in the harsh conditions of space.

The ZEUS project, or Zero-loss Energy harvesting Using nanowire solar cells in Space, focuses on creating radiation-resistant photovoltaic cells that can efficiently absorb solar energy. Nanowires, which are needle-shaped structures just 200 nanometers in diameter-much thinner than a human hair-allow for high resistance to radiation and optimal light absorption.



“Covering approximately 10 percent of a surface with active material is all that is needed to absorb as much light as a thin layer covering the entire surface of the same material would do,” explained Enrique Barrigon, professor of Applied Physics I at UMA and the project lead at the university.



Currently, nanowire solar cells used in space achieve around 15% efficiency. ZEUS aims to boost this significantly, potentially reaching up to 47% efficiency by utilizing advanced III-V semiconductor materials. The project also explores transferring these solar cells to flexible, lightweight substrates, which could be used to create large deployable photovoltaic panels for space applications.



In addition to its focus on technical innovation, the ZEUS project emphasizes environmental sustainability, including decarbonization and the efficient use of critical raw materials. Professor Barrigon highlighted that the project not only seeks to demonstrate the commercial viability of nanowire solar cells but also to assess their environmental impact, particularly for space-based power generation systems. One potential application is increasing the power output of communications satellites.



The University of Malaga will play a key role in characterizing these advanced solar cells and conducting the tests required to ensure their durability in the space environment.



The Horizon EIC Pathfinder Challenges program supports pioneering technologies like ZEUS that could shape the future by enabling the development of revolutionary technologies. The University of Malaga is also involved in other projects under this program, including ‘BioRobot-MiniHeart’ and ‘SONICOM,’ furthering its contributions to cutting-edge innovation.



Research Project:Zero-loss Energy harvesting Using nanowire solar cells in Space (ZEUS)


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Photovoltaic upgrade in Jiaxing, China significantly boosts power output

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Photovoltaic upgrade in Jiaxing, China significantly boosts power output


Photovoltaic upgrade in Jiaxing, China significantly boosts power output

by Simon Mansfield

Sydney, Australia (SPX) Oct 09, 2024






The distributed photovoltaic “trade-in” project at the administrative center in Haining city, Jiaxing, Zhejiang province, has significantly increased power generation capacity without expanding space. Launched on Sept 9, the project marks the first of its kind in Zhejiang, following the release of the “Implementation Plan for Large-scale Equipment Renewal in Key Energy Fields” by the National Development and Reform Commission and National Energy Administration on Aug 21.

As China’s installed photovoltaic capacity grows, the issue of recycling aging photovoltaic panels is becoming increasingly important. The “Plan” emphasizes the need to renew and recycle photovoltaic equipment, enhance grid-forming capabilities, and boost power generation efficiency using advanced digital and power electronics technologies.



Haining city, as part of its ambitious new energy development strategy, has set a goal of installing 300,000 kilowatts of photovoltaic capacity annually, aiming for 350,000 kilowatts. By 2026, the city expects to exceed 2 million kilowatts of installed photovoltaic capacity, with an annual green electricity output surpassing 2 billion kilowatt-hours. A key part of this plan involves upgrading older photovoltaic systems to improve both capacity and efficiency.



In 2023, State Grid Zhejiang Electric Power began mapping and assessing installed photovoltaic systems across Haining, from residential rooftops to commercial buildings. The goal was to develop a trade-in program for these systems. The project on the administrative center’s roof is the first pilot under this initiative. It involves replacing 888 P-type 270-watt modules with 731 N-type 590-watt modules, increasing capacity from 237.6 kilowatts to 431.29 kilowatts.



“This helps improve the power generation efficiency and energy utilization efficiency of photovoltaic power stations,” said Chen Huajie, the project leader. The upgraded system is expected to generate 470,000 kilowatt-hours of electricity annually, enough to meet the needs of 100 households in the region. Over its remaining lifespan, it will produce 4.5 million kilowatt-hours of new green electricity, significantly reducing carbon dioxide and sulfur dioxide emissions.



Zhong Jiewen of State Grid Zhejiang Electric Power commented that this pilot project would serve as a model for future initiatives, promoting sustainable economic and environmental development in the region.


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Solar-powered desalination system requires no extra batteries

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Solar-powered desalination system requires no extra batteries


Solar-powered desalination system requires no extra batteries

by Jennifer Chu | MIT News

Boston MA (SPX) Oct 09, 2024






MIT engineers have built a new desalination system that runs with the rhythms of the sun.

The solar-powered system removes salt from water at a pace that closely follows changes in solar energy. As sunlight increases through the day, the system ramps up its desalting process and automatically adjusts to any sudden variation in sunlight, for example by dialing down in response to a passing cloud or revving up as the skies clear.



Because the system can quickly react to subtle changes in sunlight, it maximizes the utility of solar energy, producing large quantities of clean water despite variations in sunlight throughout the day. In contrast to other solar-driven desalination designs, the MIT system requires no extra batteries for energy storage, nor a supplemental power supply, such as from the grid.



The engineers tested a community-scale prototype on groundwater wells in New Mexico over six months, working in variable weather conditions and water types. The system harnessed on average over 94 percent of the electrical energy generated from the system’s solar panels to produce up to 5,000 liters of water per day despite large swings in weather and available sunlight.



“Conventional desalination technologies require steady power and need battery storage to smooth out a variable power source like solar. By continually varying power consumption in sync with the sun, our technology directly and efficiently uses solar power to make water,” says Amos Winter, the Germeshausen Professor of Mechanical Engineering and director of the K. Lisa Yang Global Engineering and Research (GEAR) Center at MIT. “Being able to make drinking water with renewables, without requiring battery storage, is a massive grand challenge. And we’ve done it.”



The system is geared toward desalinating brackish groundwater – a salty source of water that is found in underground reservoirs and is more prevalent than fresh groundwater resources. The researchers see brackish groundwater as a huge untapped source of potential drinking water, particularly as reserves of fresh water are stressed in parts of the world. They envision that the new renewable, battery-free system could provide much-needed drinking water at low costs, especially for inland communities where access to seawater and grid power are limited.



“The majority of the population actually lives far enough from the coast, that seawater desalination could never reach them. They consequently rely heavily on groundwater, especially in remote, low-income regions. And unfortunately, this groundwater is becoming more and more saline due to climate change,” says Jonathan Bessette, MIT PhD student in mechanical engineering. “This technology could bring sustainable, affordable clean water to underreached places around the world.”



The researchers report details the new system in a paper appearing in Nature Water. The study’s co-authors are Bessette, Winter, and staff engineer Shane Pratt.



Pump and flow

The new system builds on a previous design, which Winter and his colleagues, including former MIT postdoc Wei He, reported earlier this year. That system aimed to desalinate water through “flexible batch electrodialysis.”



Electrodialysis and reverse osmosis are two of the main methods used to desalinate brackish groundwater. With reverse osmosis, pressure is used to pump salty water through a membrane and filter out salts. Electrodialysis uses an electric field to draw out salt ions as water is pumped through a stack of ion-exchange membranes.



Scientists have looked to power both methods with renewable sources. But this has been especially challenging for reverse osmosis systems, which traditionally run at a steady power level that’s incompatible with naturally variable energy sources such as the sun.



Winter, He, and their colleagues focused on electrodialysis, seeking ways to make a more flexible, “time-variant” system that would be responsive to variations in renewable, solar power.



In their previous design, the team built an electrodialysis system consisting of water pumps, an ion-exchange membrane stack, and a solar panel array. The innovation in this system was a model-based control system that used sensor readings from every part of the system to predict the optimal rate at which to pump water through the stack and the voltage that should be applied to the stack to maximize the amount of salt drawn out of the water.



When the team tested this system in the field, it was able to vary its water production with the sun’s natural variations. On average, the system directly used 77 percent of the available electrical energy produced by the solar panels, which the team estimated was 91 percent more than traditionally designed solar-powered electrodialysis systems.



Still, the researchers felt they could do better.



“We could only calculate every three minutes, and in that time, a cloud could literally come by and block the sun,” Winter says. “The system could be saying, ‘I need to run at this high power.’ But some of that power has suddenly dropped because there’s now less sunlight. So, we had to make up that power with extra batteries.”



Solar commands

In their latest work, the researchers looked to eliminate the need for batteries, by shaving the system’s response time to a fraction of a second. The new system is able to update its desalination rate, three to five times per second. The faster response time enables the system to adjust to changes in sunlight throughout the day, without having to make up any lag in power with additional power supplies.



The key to the nimbler desalting is a simpler control strategy, devised by Bessette and Pratt. The new strategy is one of “flow-commanded current control,” in which the system first senses the amount of solar power that is being produced by the system’s solar panels. If the panels are generating more power than the system is using, the controller automatically “commands” the system to dial up its pumping, pushing more water through the electrodialysis stacks. Simultaneously, the system diverts some of the additional solar power by increasing the electrical current delivered to the stack, to drive more salt out of the faster-flowing water.



“Let’s say the sun is rising every few seconds,” Winter explains. “So, three times a second, we’re looking at the solar panels and saying, ‘Oh, we have more power – let’s bump up our flow rate and current a little bit.’ When we look again and see there’s still more excess power, we’ll up it again. As we do that, we’re able to closely match our consumed power with available solar power really accurately, throughout the day. And the quicker we loop this, the less battery buffering we need.”



The engineers incorporated the new control strategy into a fully automated system that they sized to desalinate brackish groundwater at a daily volume that would be enough to supply a small community of about 3,000 people. They operated the system for six months on several wells at the Brackish Groundwater National Research Facility in Alamogordo, New Mexico. Throughout the trial, the prototype operated under a wide range of solar conditions, harnessing over 94 percent of the solar panel’s electrical energy, on average, to directly power desalination.



“Compared to how you would traditionally design a solar desal system, we cut our required battery capacity by almost 100 percent,” Winter says.



The engineers plan to further test and scale up the system in hopes of supplying larger communities, and even whole municipalities, with low-cost, fully sun-driven drinking water.



“While this is a major step forward, we’re still working diligently to continue developing lower cost, more sustainable desalination methods,” Bessette says.



“Our focus now is on testing, maximizing reliability, and building out a product line that can provide desalinated water using renewables to multiple markets around the world,” Pratt adds.



The team will be launching a company based on their technology in the coming months.



This research was supported in part by the National Science Foundation, the Julia Burke Foundation, and the MIT Morningside Academy of Design. This work was additionally supported in-kind by Veolia Water Technologies and Solutions and Xylem Goulds.



Research Report:Direct-drive photovoltaic electrodialysis via flow-commanded current control



Research Report:Flexible batch electrodialysis for low-cost solar-powered brackish water desalination


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