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Harnessing sunlight to fuel the future through covalent organic frameworks

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Harnessing sunlight to fuel the future through covalent organic frameworks

Be it rising fuel prices or failures in electricity power grids, the consequences of global energy crisis are hard to ignore. The need for alternate fuel sources is greater than ever, but, despite the popularity of solar panels, a vast amount of solar energy goes untapped. Now, a multinational team of researchers explore existing research on covalent organic frameworks (COFs), a new class of light-absorbing compounds, as a potential solution for efficient solar-driven fuel production.

Photocatalysts absorb energy from light to make a chemical reaction happen. The best known photocatalyst is perhaps chlorophyll, the green pigment in plants that helps turn sunlight into carbohydrates. While carbohydrates may be falling out of favor, photocatalysis is garnering more attention than ever. In a photocatalytic process, light falls on a photocatalyst, increases the energy of its electrons and causes them to break their bonds and move freely through the catalyst.

These “excited” electrons then react with the raw materials of a chemical reaction to produce desired products. A top priority in the field of alternate energy research is using photocatalysts to convert solar energy to fuel, a process called “solar-to-fuel production.”

In an article published in Coordination Chemistry Reviews, Dr. Changlei Xia from Nanjing Forestry University, China; Dr. Kent Kirlikovali from Northwestern University, USA; Dr. Thi Hong Chuong Nguyen, Dr. Xuan Cuong Nguyen, Dr. Quoc Ba Tran, and Dr. Chinh Chien Nguyen from Duy Tan University, Vietnam; Dr. Minh Khoa Duong and Dr. Minh Tuan Nguyen Dinh from The University of Da Nang, Vietnam; Dr. Dang Le Tri Nguyen from Ton Duc Thang University, Vietnam; Dr. Pardeep Singh and Dr. Pankaj Raizada from Shoolini University, India; Dr. Van-Huy Nguyen from Binh Duong University, Vietnam; Dr. Soo Young Kim and Dr. Quyet Van Le from Korea University, South Korea; Dr. Laxman Singh from Patliputra University, India; and Dr. Mohammadreza Shokouhimer from Seoul National University, South Korea, have highlighted the potential of covalent organic frameworks (COFs), a new class of light-absorbing materials, in solar-to-fuel production.

As Dr. Pardeep Singh explains, “Solar energy has been successfully tapped to make electricity, but we are not yet able to efficiently make liquid fuels from it. These solar fuels, like hydrogen, could be an abundant supply of sustainable, storable, and portable energy.”

The specialty of COFs lies in their ability to improve catalysis and add special substituent molecules called “functional groups” to their structure, providing a way around the limitations of existing photocatalysts. This is due to certain favorable properties of COFs such as chemical stability, controllable porosity, and strong electron delocalization, which make them extra stable.

Like the name suggests, COFs consist of organic molecules that are bonded together into a structure that can be tailored to suit various applications. Moreover, strong electron delocalization means that, unlike in semiconductor photocatalysts, the excited electrons recombine midway only infrequently, resulting in more excited electrons for the chemical reaction. Since these reactions occur at the surface of the photocatalyst, the increased surface area and modifiable porosity of COFs is a huge advantage.

COF-photocatalysts find application in the conversion of water to hydrogen, and the production of methane from carbon dioxide, thus promising the dual benefit of producing fuel and mitigating global warming. Furthermore, they can even help with nitrogen fixation, plastics production, and storage of gases.

A new kind of COF, covalent triazine frameworks (CTFs), are currently at the cutting-edge of hydrogen production research. CTFs have 20-50 times the ability to produce hydrogen, compared to graphitic photocatalysts, making them a very promising option for future fuel production.

However, before we put the solar-powered cart before the horse, it is important to note that COF-based photocatalysts are at an early stage of development and still do not produce fuel as efficiently as their semiconductor-based counterparts. Nevertheless, their outstanding properties and structural diversity make them promising candidates for future solar-to-fuel research and a viable solution for the ongoing energy crisis. “The most essential issue is to explore robust COFs-derived catalysts for the desired applications. It can be expected that COF-based photocatalysts will achieve a new milestone in the coming years,” concludes an optimistic Dr. Pankaj Raizada.

Research Report: “The Emerging Covalent Organic Frameworks (COFs) for Solar-Driven Fuels Production”

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Research team achieves significant solar cell efficiency milestone

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Research team achieves significant solar cell efficiency milestone


Research team achieves significant solar cell efficiency milestone

by Simon Mansfield

Sydney, Australia (SPX) May 26, 2024






A research team has created a tandem solar cell using antimony selenide as the bottom cell material and a hybrid perovskite material as the top cell, achieving over 20 percent power conversion efficiency. This advancement highlights antimony selenide’s potential for bottom cell applications.

Photovoltaic technology converts sunlight into electricity, offering a clean energy source. Scientists aim to enhance the efficiency of solar cells, achieving over 20 percent in conventional single-junction cells. Surpassing the Shockley-Queisser limit in these cells would be costly, but tandem solar cells can overcome this limit by stacking materials.



The team focused on antimony selenide for tandem cells, traditionally used in single-junction cells. “Antimony selenide is a suitable bottom cell material for tandem solar cells. However, because of the rarity of reported tandem solar cells using it as a bottom cell, little attention has been paid to its application. We assembled a tandem solar cell with high conversion efficiency using it as the bottom cell to demonstrate the potential of this material,” said Tao Chen, professor of Materials Science and Engineering at the University of Science and Technology of China.



Tandem cells absorb more sunlight than single-junction cells, converting more light into electricity. The team created perovskite/antimony selenide tandem cells with a transparent conducting electrode, optimizing the spectral response and achieving over 17 percent efficiency. By optimizing the antimony selenide bottom cell, they reached 7.58 percent efficiency.



The assembled four-terminal tandem cell achieved 20.58 percent efficiency, higher than independent subcells. The tandem cell is stable and uses nontoxic elements. “This work provides a new tandem device structure and demonstrates that antimony selenide is a promising absorber material for bottom cell applications in tandem solar cells,” said Chen.



The team aims to develop an integrated two-terminal tandem cell and further improve performance. “The high stability of antimony selenide provides great convenience for the preparation of two-terminal tandem solar cell, which means that it may have good results when paired with quite a few different types of top cell materials.”



Research Report:Sb2Se3 as a bottom cell material for efficient perovskite/Sb2Se3 tandem solar cells


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Flower or power? Campaigners fear lithium mine could kill rare plant

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Flower or power? Campaigners fear lithium mine could kill rare plant


Flower or power? Campaigners fear lithium mine could kill rare plant

By Romain FONSEGRIVES

Rhyolite Ridge, United States (AFP) May 23, 2024






Delicate pink buds sway in the desert breeze, pregnant with yellow pompoms whose explosion will carpet the dusty corner of Nevada that is the only place on Earth where they exist.

Under their roots lie vast reserves of lithium, vital for the rechargeable electric car batteries that will reduce planet-heating pollution.

But campaigners fear the extraction of the precious metal could destroy the flower’s tiny habitat.

“This mine is going to cause extinction,” says Patrick Donnelly, an environmentalist who works at the Center for Biological Diversity, a non-governmental organization.

“They somehow claim that they’re not harming the (plant). But can you imagine if someone built an open-pit mine 200 feet from your house? Wouldn’t that affect your life profoundly?”

The plant in question is Tiehm’s buckwheat.

There are only around 20,000 known specimens, growing in a few very specific places on a total surface area equivalent to around five soccer fields.

In 2022, the wildflower was classified as endangered by US federal authorities, with mining cited as a major threat to its survival.

The plant and the lithium reserve on which it grows embody one of the key challenges and contradictions of the global climate struggle: how much damage can we inflict on the natural world as we seek to halt or reverse the problems we have already created?

– ‘Coexist’ –

Bernard Rowe, boss of Australian miner Ioneer, which holds the mineral rights to the area, says the lithium produced at Rhyolite Ridge “will be sufficient to provide batteries for about 370,000 vehicles” a year.

“We’ll do that year-on-year for 26 years,” he said.

Those nearly 10 million vehicles will go a long way towards meeting the goal President Joe Biden has set of cutting down the nation’s fleet of gas-guzzlers as a way to slash US production of planet-warming pollutants.

So-called zero-emission cars make up around 7.5 percent of new vehicle sales in the United States today — more than double the percentage just a few years earlier.

In California, the figure is more than 20 percent.

And while expansion in the sector has slowed, the category remains the fastest-growing, according to Kelley Blue Book.

And it’s not only in the United States: Global demand for lithium will increase five to seven times by 2030, according to the International Energy Agency.

The difficulty for US manufacturers is that much of the world’s lithium supply is dominated by strategic rival China, as well as Australia and Chile.

“The United States has very, very little domestic production,” said Rowe.

“So it’s important to develop a domestic supply chain to allow for that energy transition, and Rhyolite Ridge will be an integral part of that.”

Ioneer’s plans show that over the years the mine is in operation — it is projected to start producing lithium in late 2027 — around a fifth of the plant’s habitat will be directly affected.

But the company, which has spent $2.5 million researching the plant, says mining will not affect its survival; it is already growing well in greenhouses and biologists think it can be replanted.

“We’re very confident that the mine and Tiehm’s buckwheat can coexist,” Rowe said.

– ‘Greenwashing’ –

Donnelly counters that Ioneer is “basically greenwashing extinction.”

“They’re saying. ‘We’re going to save this plant,’ when actually they are going to send it to its doom,” he said.

Under the company’s plans, the strip mine will use hundreds of trucks, which Donnelly says will raise clouds of dust that will affect photosynthesis and harm the insects that pollinate the plants.

Ioneer says it has already planned mitigation methods, like dust curtains, and keeping the roads wet.

Still, Donnelly says, why not just move the mine? But Rowe counters that it’s not as simple as just digging somewhere else.

Ioneer has invested $170 million since 2016 to demonstrate the feasibility of this site, which it believes is one of the best around.

“Many of these other deposits haven’t had that amount of work, so they’re not viable alternatives to a project like this,” he said.

The US Department of Energy has offered Ioneer a $700 million loan for the project, if the Bureau of Land Management signs off on an operating permit.

Donnelly insists the issue is not just the future of one obscure wildflower, but rather just one example of large-scale biodiversity loss that is threatening millions of plants and animals.

“If we solve the climate crisis, but we drive everything extinct while we do it, we’re still going to lose our world,” he said.

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Tesla breaks ground on huge Shanghai battery plant

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Tesla breaks ground on huge Shanghai battery plant


Tesla breaks ground on huge Shanghai battery plant

by AFP Staff Writers

Shanghai (AFP) May 23, 2024






Tesla broke ground on a massive battery factory in Shanghai on Thursday, Chinese state media reported, making it the US electric car giant’s second plant in the financial hub.

The project was announced last April after boss Elon Musk presented a vague but ambitious plan to investors to turbocharge growth.

However, the company last month reported a 55 percent drop in quarterly earnings, reflecting a decline in EV sales in an intensively competitive market.

The new Shanghai factory should make 10,000 units per year of Tesla’s Megapack batteries, state news agency Xinhua said.

Tesla says Megapacks are intended to store energy and stabilise supply for power grids, with each unit able to store more than three megawatt-hours of power.

The factory is expected to start mass production in 2025, state media said in May.

“I believe the new plant is a milestone for both Shanghai and Tesla,” the company’s vice president Tao Lin told Xinhua.

“In a more open environment, we can… supply the global market with large-scale energy-storage batteries manufactured in China.”

Musk has extensive business interests in China and is a fairly frequent visitor.

In April, he met Chinese Premier Li Qiang, and received a key security clearance for Tesla’s locally produced EVs.

Musk’s interests in China have long raised eyebrows in Washington — President Joe Biden has said in the past that his links to foreign countries were “worthy” of scrutiny.

The battery plant will be Tesla’s second in the Chinese city after its enormous Shanghai Gigafactory, which broke ground in 2019.

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