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High Proton Conductivity Achieved in Novel Perovskite Materials

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High Proton Conductivity Achieved in Novel Perovskite Materials


High Proton Conductivity Achieved in Novel Perovskite Materials

by Riko Seibo

Tokyo, Japan (SPX) May 31, 2024






Scientists at Tokyo Institute of Technology (Tokyo Tech) have developed a new perovskite, BaSc0.8W0.2O2.8, that demonstrates high proton conduction at low and intermediate temperatures. This advancement is achieved through donor doping with large W6+ cations, which increases water uptake and reduces proton trapping. These findings could lead to the development of novel perovskites for protonic ceramic fuel cells (PCFCs) and proton-conducting electrolysis cells (PCECs).

Fuel cells are becoming critical in converting chemical energy into electrical energy as part of global clean energy initiatives. Among these, PCFCs, which use solid electrolytes, offer safety and stability benefits. However, conventional perovskite electrolytes in PCFCs suffer from low proton conductivity at low and intermediate temperatures.



A research team led by Professor Masamoto Yashima at Tokyo Tech, in collaboration with High Energy Accelerator Research Organization (KEK), investigated this issue. Their study, published in the Journal of Materials Chemistry A on May 3, 2024, addresses the low conductivity of conventional proton conductors caused by proton trapping and low proton concentration.



“A major problem with the conventional proton conductors is a phenomenon known as proton trapping, in which protons are trapped by acceptor dopant via electrostatic attraction between the dopant and proton,” Yashima explained. “Another major problem among such proton conductors would also be their low proton concentration due to the small amount of oxygen vacancies.”



To overcome these challenges, the researchers developed BaSc0.8W0.2O2.8 with high oxygen vacancies, resulting in a higher proton concentration. Full hydration of the material converts it to BaSc0.8W0.2O3H0.4, enabling high proton conductivity due to increased water uptake and reduced proton trapping. The large W6+ dopant’s positive charge repels protons, facilitating their migration across the material, as confirmed by molecular dynamics simulations.



This study provides fundamental design principles for future proton-conducting perovskites. “The stabilization of perovskites with disordered intrinsic oxygen vacancies and full hydration enabled by doping of large donor dopant could be an effective strategy towards next-generation proton conductors,” remarked Yashima.



These proton conductors are essential for both PCFCs and PCECs, contributing to sustainable energy technologies.



Research Report:High proton conduction by full hydration in highly oxygen deficient perovskite


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India mandates local-only solar energy components from 2026

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India mandates local-only solar energy components from 2026





India mandates local-only solar energy components from 2026

by AFP Staff Writers

New Delhi (AFP) Dec 10, 2024






Indian clean energy companies will only be able to use solar modules built locally from June 2026, according to a government order apparently aimed at reducing Chinese imports.

Clean energy sector leaders in India, including ventures by conglomerates Reliance Enterprises and Tata Power, rely on Chinese vendors as their major suppliers.

As much as 70 percent of India’s solar power generation capacity is powered by Chinese equipment, according to industry estimates.

Indian companies are already required by law to use locally made solar panels in government projects.

The new rule mandates that only modules made from locally built photovoltaic cells, which convert light energy into electricity, can be used in projects with a bid deadline after Monday’s order.

“This condition will have to be followed irrespective of the date of commissioning,” said the order, issued by India’s renewable energy ministry.

The government is yet to issue the list of approved manufacturers of solar cells because “the installed capacity of solar cells in the country was lower than demand”.

But “with installed capacity of solar cells in the country expected to increase substantially in next year”, a list of approved manufacturers will now be released, the order said.

India’s solar equipment manufacturing space has made rapid strides in recent years.

A report by Bengaluru-based consulting firm Mercom India said the country’s solar panel production was expected to reach 95 gigawatts by the end of 2025.

India added 13.3 gigawatts of solar equipment manufacturing capacity in the first half of 2024, according to the same report.

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Stellantis, Chinese firm CATL plan $4bn battery plant in Spain

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Stellantis, Chinese firm CATL plan bn battery plant in Spain





Stellantis, Chinese firm CATL plan $4bn battery plant in Spain

By Valentin Bontemps with Frederique Pris in Paris

Madrid (AFP) Dec 10, 2024






Car giant Stellantis and Chinese manufacturer CATL said Tuesday they would build a $4.3-billion factory to make electric vehicle batteries in Spain, the latest bid to boost Europe’s troubled EV drive.

They said they aim to start production by the end of 2026 at the site in the northern city of Zaragoza.

It “could reach up to 50 GWh capacity, subject to the evolution of the electrical market in Europe and continued support from authorities in Spain and the European Union”, the companies said in a statement.

The two firms signed an agreement in 2023 to produce battery parts for the manufacture of electric vehicles in Europe.

CATL, which has received robust financial support from Beijing, has launched two other European factories, in Germany and Hungary.

Its chief executive Robin Zeng met late on Monday with Spain’s Prime Minister Pedro Sanchez, ahead of the announcement of the 4.1-billion-euro deal.

In a message on X, the Socialist premier thanked the presidents of the two firms for their “firm commitment” to Spain, adding he was “very pleased”.

During a visit to China in September, Sanchez urged the European Union to “reconsider” a plan to impose tariffs on Chinese electric cars, calling for a “compromise” between the economic powerhouses.

Spanish Economy Minister Carlos Cuerpo called the announcement “excellent news for industry and employment in our country”.

Spain has been playing a growing role in European vehicle production, assembling 1.87 million cars in 2023 — the second-biggest producer in the continent after Germany, according to the European Automobile Manufacturers’ Association.

– Bumpy patch for carmakers –

The announcement comes at a turbulent time in the car industry as countries seek to switch to low-carbon electric vehicles to curb the climate crisis.

Sweden’s financially strained electric car battery maker Northvolt last month announced the resignation of its chief executive Peter Carlsson.

That came hours after the company sought bankruptcy protection in the United States.

The company said in September it was slashing 1,600 jobs — a quarter of its staff — and suspending the expansion of its site as it struggled with strained finances and a slowdown in demand.

The company had been seen as a cornerstone of European attempts to catch up with China and the United States in the production of battery cells, a crucial component of lower-emission cars.

Stellantis’s former chief executive Carlos Tavares also resigned on December 1, with the company signalling differences over how to save the group’s slumping profits.

Like other auto groups, Stellantis has blamed competition from China and the difficult transition to electric cars for much of its troubles.

It announced on November 26 that it was closing a factory at Luton in England with the loss of 1,100 jobs.

– ‘High-quality’ EVs –

Founded in 2011 in Ningde, eastern China, CATL produces more than a third of the electric vehicle batteries sold in the world.

Italian-US-French company Stellantis produces 14 brands including Fiat, Peugeot-Citroen, Opel, Maserati, Chrysler, Ram and Jeep.

The Zaragoza plant will make lithium iron phosphate (LFP) batteries, which are cheaper to produce but less powerful compared with nickel manganese cobalt (NMC) ones, the other current mainstream technology.

The companies said the factory, which will be designed to be completely carbon neutral, would enable Stellantis “to offer more high-quality, durable and affordable battery-electric passenger cars, crossovers and SUVs”.

Stellantis chairman John Elkann said in the statement that the venture “will bring innovative battery production to a manufacturing site that is already a leader in clean and renewable energy”.

Zeng said CATL’s goal was “to make zero-carbon technology accessible across the globe”.

The deal is expected to be closed in 2025, subject to regulation.

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Existing EV batteries may last significantly longer under real-world conditions

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Existing EV batteries may last significantly longer under real-world conditions





Existing EV batteries may last significantly longer under real-world conditions

by Clarence Oxford

Los Angeles CA (SPX) Dec 10, 2024






Electric vehicle (EV) batteries subjected to typical real-world driving scenarios-such as heavy traffic, urban commutes, and long highway trips-could last up to 40% longer than previously projected, according to new research from the SLAC-Stanford Battery Center, a collaboration between Stanford University’s Precourt Institute for Energy and SLAC National Accelerator Laboratory. This finding suggests EV owners may delay the costly replacement of battery packs or the purchase of new vehicles for several more years than expected.

Traditionally, battery scientists have tested EV batteries in labs using a constant charge-discharge cycle. While effective for quick evaluations of new designs, this method does not accurately reflect the varied usage patterns of everyday drivers, the study published in *Nature Energy* on Dec. 9 reveals.



Although battery costs have fallen by approximately 90% over the past 15 years, they still represent about one-third of an EV’s price. This research could provide reassurance to current and prospective EV owners about the longevity of their vehicle’s batteries.



“We’ve not been testing EV batteries the right way,” said Simona Onori, the study’s senior author and an associate professor at Stanford’s Doerr School of Sustainability. “To our surprise, real driving with frequent acceleration, braking, stopping for errands, and extended rest periods helps batteries last longer than previously thought based on industry-standard tests.”

Real-World Driving Profiles Improve Battery Lifespan

The researchers developed four distinct EV discharge profiles, ranging from constant discharge to dynamic patterns based on actual driving data. Testing 92 commercial lithium-ion batteries over two years, they found that batteries subjected to realistic driving scenarios demonstrated significantly improved longevity.

Machine learning algorithms were crucial in analyzing the extensive data, revealing that certain driving behaviors, like sharp accelerations, slowed battery degradation. This contradicted prior assumptions that acceleration peaks harm EV batteries. “Pressing the pedal hard does not speed up aging. If anything, it slows it down,” explained Alexis Geslin, one of the study’s lead authors and a PhD candidate in materials science and computer science at Stanford.

Aging from Use vs. Time

The study differentiated between battery aging caused by charge-discharge cycles and aging from time alone. While frequent cycling dominates battery aging for commercial vehicles like buses or delivery vans, time-induced aging becomes a larger factor for personal EVs, which are often parked and idle.



“We battery engineers have assumed that cycle aging is much more important than time-induced aging,” said Geslin. “For consumers using their EVs for daily errands but leaving them unused most of the time, time becomes the predominant aging factor.”



The researchers identified an optimal discharge rate balancing both time and cycle aging for the batteries tested, which aligns with typical consumer driving habits. Manufacturers could update battery management software to incorporate these findings, potentially extending battery lifespan under normal conditions.

Implications for the Future

Evaluating new battery chemistries and designs under realistic conditions is critical for future advancements, said Le Xu, a postdoctoral scholar in energy science and engineering. “Researchers can now revisit presumed aging mechanisms at the chemistry, materials, and cell levels to deepen their understanding,” Xu added.



The study’s principles could apply beyond EV batteries to other energy storage systems, plastics, solar cells, and biomaterials where aging is a key concern. “This work highlights the power of integrating multiple areas of expertise-from materials science and modeling to machine learning-to drive innovation,” Onori concluded.



Research Report:Dynamic cycling enhances battery lifetime


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