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Improved polymer additive enhances perovskite solar cells

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Improved polymer additive enhances perovskite solar cells


Improved polymer additive enhances perovskite solar cells

by Simon Mansfield

Sydney, Australia (SPX) May 16, 2024






Perovskite solar cells, known for their lightweight and flexible nature, are inexpensive and easy to manufacture. They are seen as a promising technology that can be attached to various surfaces. However, these solar cells currently lack durability and efficiency. New research highlights how adding a polymerized ionic liquid to the metal halide perovskite material can improve their performance, potentially facilitating wider adoption of perovskite solar cells.

“The commonly employed solution processing method for fabricating perovskite layers introduces many defects in both the bulk and surface of the perovskite layer. These intrinsic defects within the perovskite absorption layer pose a significant constraint on the overall performance of the devices. Additive engineering has been demonstrated to be effective as a strategy for defect passivation and performance enhancement in perovskite solar cells,” said Qi Cao, a researcher at Northwestern Polytechnical University in Xi’an, China.



Researchers are enhancing the properties of ionic liquids by creating polymerized versions. In this study, they synthesized a poly ionic liquid called poly4-styrenesulfonyl(trifluoremethylsulfonyl)imidepyridine (PSTSIPPyri).



The addition of PSTSIPPyri to the perovskite solar cell helps prevent halide ion migration, maintains the crystal structure, and improves the solar cell’s stability by fixing organic and halide ions.



“To date, researchers have devoted considerable attention to the meticulous selection of additives that enhance the performance of perovskite solar cells. Among these, ionic liquids have received widespread attention. Ionic bonds in ionic liquids tend to be stronger and more stable, and they offer various tunable properties, including viscosity, polarity, and conductivity,” said Xuanhua Li, a researcher at Northwestern Polytechnical University. “This tunability makes it possible to fine-tune the ionic liquid properties to meet the specific requirements of the perovskite film, thereby optimizing device performance.”



Testing of the PSTSIPPyri additive involved aging perovskite films for 300 hours at 85C and 60% relative humidity. The enhanced perovskite film showed a slower rate of change than the control film. It also retained 84.5% of its efficiency after 1000 hours in a high humidity, high heat environment, compared to 43.6% for the control.



Long-term durability tests showed that with PSTSIPPyri, the perovskite solar cell maintained 87.6% of its power conversion efficiency after 1,500 hours of continuous light, while the control only maintained 61.1%.



“Incorporating PSTSIPPyri as an additive leads to a significant enhancement in the power conversion efficiency of inverted perovskite solar cells from 22.06% to 24.62%. They also demonstrate excellent long-term operational stability,” said Cao. “This strategy illustrates the potential of poly ionic liquids as a promising additive for perovskite solar cells, offering both high performance and stability.”



Other contributors include Xingyuan Chen, Tong Wang, Jiabao Yang, Xingyu Pu, Hui Chen, Bingxiu Xue, and Jianbo Yin at Northwestern Polytechnical University in Xi’an, China; Long Jiang at the CNPC Tubular Goods Research Institute in Xi’an, China.



Research Report:Efficiency enhancement to 24.62% in inverted perovskite solar cells through poly (ionic liquid) bulk modification


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So you want to build a solar or wind farm? Here’s how to decide where

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So you want to build a solar or wind farm? Here’s how to decide where





So you want to build a solar or wind farm? Here’s how to decide where

by David L. Chandler | MIT News

Boston MA (SPX) Dec 08, 2024






Deciding where to build new solar or wind installations is often left up to individual developers or utilities, with limited overall coordination. But a new study shows that regional-level planning using fine-grained weather data, information about energy use, and energy system modeling can make a big difference in the design of such renewable power installations. This also leads to more efficient and economically viable operations.

The findings show the benefits of coordinating the siting of solar farms, wind farms, and storage systems, taking into account local and temporal variations in wind, sunlight, and energy demand to maximize the utilization of renewable resources. This approach can reduce the need for sizable investments in storage, and thus the total system cost, while maximizing availability of clean power when it’s needed, the researchers found.



The study, appearing in the journal Cell Reports Sustainability, was co-authored by Liying Qiu and Rahman Khorramfar, postdocs in MIT’s Department of Civil and Environmental Engineering, and professors Saurabh Amin and Michael Howland.



Qiu, the lead author, says that with the team’s new approach, “we can harness the resource complementarity, which means that renewable resources of different types, such as wind and solar, or different locations can compensate for each other in time and space. This potential for spatial complementarity to improve system design has not been emphasized and quantified in existing large-scale planning.”



Such complementarity will become ever more important as variable renewable energy sources account for a greater proportion of power entering the grid, she says. By coordinating the peaks and valleys of production and demand more smoothly, she says, “we are actually trying to use the natural variability itself to address the variability.”



Typically, in planning large-scale renewable energy installations, Qiu says, “some work on a country level, for example saying that 30 percent of energy should be wind and 20 percent solar. That’s very general.” For this study, the team looked at both weather data and energy system planning modeling on a scale of less than 10-kilometer (about 6-mile) resolution. “It’s a way of determining where should we, exactly, build each renewable energy plant, rather than just saying this city should have this many wind or solar farms,” she explains.



To compile their data and enable high-resolution planning, the researchers relied on a variety of sources that had not previously been integrated. They used high-resolution meteorological data from the National Renewable Energy Laboratory, which is publicly available at 2-kilometer resolution but rarely used in a planning model at such a fine scale. These data were combined with an energy system model they developed to optimize siting at a sub-10-kilometer resolution. To get a sense of how the fine-scale data and model made a difference in different regions, they focused on three U.S. regions – New England, Texas, and California – analyzing up to 138,271 possible siting locations simultaneously for a single region.



By comparing the results of siting based on a typical method vs. their high-resolution approach, the team showed that “resource complementarity really helps us reduce the system cost by aligning renewable power generation with demand,” which should translate directly to real-world decision-making, Qiu says. “If an individual developer wants to build a wind or solar farm and just goes to where there is the most wind or solar resource on average, it may not necessarily guarantee the best fit into a decarbonized energy system.”



That’s because of the complex interactions between production and demand for electricity, as both vary hour by hour, and month by month as seasons change. “What we are trying to do is minimize the difference between the energy supply and demand rather than simply supplying as much renewable energy as possible,” Qiu says. “Sometimes your generation cannot be utilized by the system, while at other times, you don’t have enough to match the demand.”



In New England, for example, the new analysis shows there should be more wind farms in locations where there is a strong wind resource during the night, when solar energy is unavailable. Some locations tend to be windier at night, while others tend to have more wind during the day.



These insights were revealed through the integration of high-resolution weather data and energy system optimization used by the researchers. When planning with lower resolution weather data, which was generated at a 30-kilometer resolution globally and is more commonly used in energy system planning, there was much less complementarity among renewable power plants. Consequently, the total system cost was much higher. The complementarity between wind and solar farms was enhanced by the high-resolution modeling due to improved representation of renewable resource variability.



The researchers say their framework is very flexible and can be easily adapted to any region to account for the local geophysical and other conditions. In Texas, for example, peak winds in the west occur in the morning, while along the south coast they occur in the afternoon, so the two naturally complement each other.



Khorramfar says that this work “highlights the importance of data-driven decision making in energy planning.” The work shows that using such high-resolution data coupled with carefully formulated energy planning model “can drive the system cost down, and ultimately offer more cost-effective pathways for energy transition.”



One thing that was surprising about the findings, says Amin, who is a principal investigator in the MIT Laboratory of Information and Data Systems, is how significant the gains were from analyzing relatively short-term variations in inputs and outputs that take place in a 24-hour period. “The kind of cost-saving potential by trying to harness complementarity within a day was not something that one would have expected before this study,” he says.



In addition, Amin says, it was also surprising how much this kind of modeling could reduce the need for storage as part of these energy systems. “This study shows that there is actually a hidden cost-saving potential in exploiting local patterns in weather, that can result in a monetary reduction in storage cost.”



The system-level analysis and planning suggested by this study, Howland says, “changes how we think about where we site renewable power plants and how we design those renewable plants, so that they maximally serve the energy grid. It has to go beyond just driving down the cost of energy of individual wind or solar farms. And these new insights can only be realized if we continue collaborating across traditional research boundaries, by integrating expertise in fluid dynamics, atmospheric science, and energy engineering.”



Research Report:Decarbonized energy system planning with high-resolution spatial representation of renewables lowers cost


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China to send batteries to Europe via route bypassing Russia: Kazakhstan

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China to send batteries to Europe via route bypassing Russia: Kazakhstan

by AFP Staff Writers

Almaty, Kazakhstan (AFP) Dec 6, 2024






China will soon send lithium-ion batteries to Europe via Kazakhstan on a trade route that bypasses sanctions-hit Russia, the Central Asian country said Friday.

Trade via the Trans-Caspian International Transport Route (TITR) that crosses the Caspian Sea has jumped since Moscow invaded Ukraine in 2022, as European countries seek to avoid imports that transit Russia.

Kazakhstan has agreed to “jointly develop” the route with Beijing, launching a “trial run for the transportation of lithium-ion batteries from China” in December, Kazakhstan’s transport ministry said Friday.

China is the world’s largest producer of lithium-ion batteries and among the top miners of the metal, which is used to power phones and electric vehicles.

“The volume of transportation from China along the TITR (in the direction of China to Europe) has exceeded the equivalent of 27,000 20-foot containers, which is 25 times more than in the same period last year,” the ministry said.

The ministry also noted an increase in goods transported between China and Kazakhstan, with both sides discussing the idea of opening new transport routes across their shared border.

Europe has looked to Central Asia as a key trading partner since Moscow launched its Ukraine offensive, triggering a barrage of Western sanctions on Moscow.

Beijing has also invested billions of dollars in building rail and road routes that traverse Central Asia, as it seeks to turn the region into a trading hub for its “New Silk Road”.

Construction is underway to build a China-Kyrgyzstan-Uzbekistan railroad that will shorten transport times between China and Europe.

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Meta pushes zero-carbon energy strategy with solar deal

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Meta pushes zero-carbon energy strategy with solar deal





Meta pushes zero-carbon energy strategy with solar deal

by AFP Staff Writers

Washington (AFP) Dec 5, 2024






Meta has signed contracts with renewable energy firm Invenergy for 760 megawatts of solar power capacity, the companies said on Thursday.

The deal is part of the Facebook-owner’s search for cleaner power sources, including nuclear, as its power needs expand, namely because of the adoption of artificial intelligence.

The project involves solar facilities in four US states and pushes Meta’s total renewable energy agreements with Chicago-based Invenergy beyond 1 gigawatt. Operations are expected to begin between 2024 and 2027.

The electricity will supply local power grids while Meta receives clean energy credits, supporting its goal of powering all operations with renewable energy.

“Energy demand is soaring,” said Invenergy Executive Vice President Ted Romaine, noting the projects will create jobs and generate “millions in local economic benefits.”

Meta’s Head of Global Energy Urvi Parekh said the agreement helps match the company’s growing power needs with clean energy sources.

Invenergy, the largest privately held clean energy developer in the US, said it has developed over 32,000 megawatts of renewable energy projects across the Americas, Europe, and Asia.

Meta announced plans on Tuesday to seek proposals for 1-4 gigawatts of new nuclear generation capacity in the US, targeting operations in the early 2030s.

The nuclear initiative aims to support Meta’s growing artificial intelligence operations and data centers while contributing to grid reliability.

Building AI consumes a tremendous amount of electricity because it involves intensive computing operations. It also emits a lot of CO2 when using power generated by coal or natural gas.

As tech companies seek energy sources to meet these demands while maintaining their zero-carbon emission commitments, the chase for nuclear, wind and solar power has intensified.

Meta’s push into nuclear power follows similar initiatives by Microsoft and Amazon that are also scrambling to find enough power to needs of their AI ambitions, while also meeting zero-carbon targets.

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