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Integrating dimensions to get more out of Moore’s Law and advance electronics
Moore’s Law, a fundamental scaling principle for electronic devices, forecasts that the number of transistors on a chip will double every two years, ensuring more computing power — but a limit exists.
In a study published today (Jan. 10) in the journal Nature, Saptarshi Das, an associate professor of engineering science and mechanics and co-corresponding author of the study, and his team suggest a remedy: seamlessly implementing 3D integration with 2D materials.
In the semiconductor world, 3D integration means vertically stacking multiple layers of semiconductor devices. This approach not only facilitates the packing of more silicon-based transistors onto a computer chip, commonly referred to as “More Moore,” but also permits the use of transistors made from 2D materials to incorporate diverse functionalities within various layers of the stack, a concept known as “More than Moore.”
With the work outlined in the study, Saptarshi and the team demonstrate feasible paths beyond scaling current tech to achieve both More Moore and More than Moore through monolithic 3D integration. Monolithic 3D integration is a fabrication process wherein researchers directly make the devices on the one below, as compared to the traditional process of stacking independently fabricated layers.
“Monolithic 3D integration offers the highest density of vertical connections as it does not rely on bonding of two pre-patterned chips — which would require microbumps where two chips are bonded together — so you have more space to make connections,” said Najam Sakib, graduate research assistant in engineering science and mechanics and co-author of the study.
Monolithic 3D integration faces significant challenges, though, according to Darsith Jayachandran, graduate research assistant in engineering science and mechanics and co-corresponding author of the study, since conventional silicon components would melt under the processing temperatures.
“One challenge is the process temperature ceiling of 450 degrees Celsius (C) for back-end integration for silicon-based chips — our monolithic 3D integration approach drops that temperate significantly to less than 200 C,” Jayachandran said, explaining that the process temperature ceiling is the maximum temperature allowed before damaging the prefabricated structures. “Incompatible process temperature budgets make monolithic 3D integration challenging with silicon chips, but 2D materials can withstand temperatures needed for the process.”
The researchers used existing techniques for their approach, but they are the first to successfully achieve monolithic 3D integration at this scale using 2D transistors made with 2D semiconductors called transition metal dichalcogenides.
The ability to vertically stack the devices in 3D integration also enabled more energy-efficient computing because it solved a surprising problem for such tiny things as transistors on a computer chip: distance.
“By stacking devices vertically on top of each other, you’re decreasing the distance between devices, and therefore, you’re decreasing the lag and also the power consumption,” said Rahul Pendurthi, graduate research assistant in engineering science and mechanics and co-corresponding author of the study.
By decreasing the distance between devices, the researchers achieved “More Moore.” By incorporating transistors made with 2D materials, the researchers met the “More than Moore” criterion as well. The 2D materials are known for their unique electronic and optical properties, including sensitivity to light, which makes these materials ideal as sensors. This is useful, the researchers said, as the number of connected devices and edge devices — things like smartphones or wireless home weather stations that gather data on the ‘edge’ of a network — continue to increase.
“‘More Than Moore’ refers to a concept in the tech world where we are not just making computer chips smaller and faster, but also with more functionalities,” said Muhtasim Ul Karim Sadaf, graduate research assistant in engineering science and mechanics and co-author of the study. “It is about adding new and useful features to our electronic devices, like better sensors, improved battery management or other special functions, to make our gadgets smarter and more versatile.”
Using 2D devices for 3D integration has several other advantages, the researchers said. One is superior carrier mobility, which refers to how an electrical charge is carried in semiconductor materials. Another is being ultra-thin, enabling the researchers to fit more transistors on each tier of the 3D integration and enable more computing power.
While most academic research involves small-scale prototypes, this study demonstrated 3D integration at a massive scale, characterizing tens of thousands of devices. According to Das, this achievement bridges the gap between academia and industry and could lead to future partnerships where industry leverages Penn State’s 2D materials expertise and facilities. The advance in scaling was enabled by the availability of high-quality, wafer-scale transition metal dichalcogenides developed by researchers at Penn State’s Two-Dimensional Crystal Consortium (2DCC-MIP), a U.S. National Science Foundation (NSF) Materials Innovation Platform and national user facility.
“This breakthrough demonstrates yet again the essential role of materials research as the foundation of the semiconductor industry and U.S. competitiveness,” said Charles Ying, program director for NSF’s Materials Innovation Platforms. “Years of effort by Penn State’s Two-Dimensional Crystal Consortium to improve the quality and size of 2D materials have made it possible to achieve 3D integration of semiconductors at a size that can be transformative for electronics.”
According to Das, this technological advancement is only the first step.
“Our ability to demonstrate, at wafer scale, a huge number of devices shows that we have been able to translate this research to a scale which can be appreciated by the semiconductor industry,” Das said. “We have put 30,000 transistors in each tier, which may be a record number. This puts Penn State in a very unique position to lead some of the work and partner with the U.S. semiconductor industry in advancing this research.”
Along with Das, Jayachandran, Pendurthi, Sadaf and Sakib, other authors include Andrew Pannone, doctoral student in engineering science and mechanics; Chen Chen, assistant research professor in 2DCC-MIP; Ying Han, postdoctoral researcher in mechanical engineering; Nicholas Trainor, doctoral student in materials science and engineering; Shalini Kumari, postdoctoral scholar; Thomas McKnight, doctoral student in materials science and engineering; Joan Redwing, director of the 2DCC-MIP and distinguished professor of materials science and engineering and of electrical engineering; and Yang Yang, assistant professor of engineering science and mechanics.
The U.S. National Science Foundation and Army Research Office supported this research.
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Early dark energy could resolve cosmology’s two biggest puzzles
A new study by MIT physicists proposes that a mysterious force known as early dark energy could solve two of the biggest puzzles in cosmology and fill in some major gaps in our understanding of how the early universe evolved.
Now, the MIT team has found that both puzzles could be resolved if the early universe had one extra, fleeting ingredient: early dark energy. Dark energy is an unknown form of energy that physicists suspect is driving the expansion of the universe today. Early dark energy is a similar, hypothetical phenomenon that may have made only a brief appearance, influencing the expansion of the universe in its first moments before disappearing entirely.
Some physicists have suspected that early dark energy could be the key to solving the Hubble tension, as the mysterious force could accelerate the early expansion of the universe by an amount that would resolve the measurement mismatch.
The MIT researchers have now found that early dark energy could also explain the baffling number of bright galaxies that astronomers have observed in the early universe. In their new study, reported in the Monthly Notices of the Royal Astronomical Society, the team modeled the formation of galaxies in the universe’s first few hundred million years. When they incorporated a dark energy component only in that earliest sliver of time, they found the number of galaxies that arose from the primordial environment bloomed to fit astronomers’ observations.
“You have these two looming open-ended puzzles,” says study co-author Rohan Naidu, a postdoc in MIT’s Kavli Institute for Astrophysics and Space Research. “We find that in fact, early dark energy is a very elegant and sparse solution to two of the most pressing problems in cosmology.”
The study’s co-authors include lead author and Kavli postdoc Xuejian (Jacob) Shen, and MIT professor of physics Mark Vogelsberger, along with Michael Boylan-Kolchin at the University of Texas at Austin, and Sandro Tacchella at the University of Cambridge.
Big city lights
Based on standard cosmological and galaxy formation models, the universe should have taken its time spinning up the first galaxies. It would have taken billions of years for primordial gas to coalesce into galaxies as large and bright as the Milky Way.
But in 2023, NASA’s James Webb Space Telescope (JWST) made a startling observation. With an ability to peer farther back in time than any observatory to date, the telescope uncovered a surprising number of bright galaxies as large as the modern Milky Way within the first 500 million years, when the universe was just 3 percent of its current age.
“The bright galaxies that JWST saw would be like seeing a clustering of lights around big cities, whereas theory predicts something like the light around more rural settings like Yellowstone National Park,” Shen says. “And we don’t expect that clustering of light so early on.”
For physicists, the observations imply that there is either something fundamentally wrong with the physics underlying the models or a missing ingredient in the early universe that scientists have not accounted for. The MIT team explored the possibility of the latter, and whether the missing ingredient might be early dark energy.
Physicists have proposed that early dark energy is a sort of antigravitational force that is turned on only at very early times. This force would counteract gravity’s inward pull and accelerate the early expansion of the universe, in a way that would resolve the mismatch in measurements. Early dark energy, therefore, is considered the most likely solution to the Hubble tension.
Galaxy skeleton
The MIT team explored whether early dark energy could also be the key to explaining the unexpected population of large, bright galaxies detected by JWST. In their new study, the physicists considered how early dark energy might affect the early structure of the universe that gave rise to the first galaxies. They focused on the formation of dark matter halos — regions of space where gravity happens to be stronger, and where matter begins to accumulate.
“We believe that dark matter halos are the invisible skeleton of the universe,” Shen explains. “Dark matter structures form first, and then galaxies form within these structures. So, we expect the number of bright galaxies should be proportional to the number of big dark matter halos.”
The team developed an empirical framework for early galaxy formation, which predicts the number, luminosity, and size of galaxies that should form in the early universe, given some measures of “cosmological parameters.” Cosmological parameters are the basic ingredients, or mathematical terms, that describe the evolution of the universe.
Physicists have determined that there are at least six main cosmological parameters, one of which is the Hubble constant — a term that describes the universe’s rate of expansion. Other parameters describe density fluctuations in the primordial soup, immediately after the Big Bang, from which dark matter halos eventually form.
The MIT team reasoned that if early dark energy affects the universe’s early expansion rate, in a way that resolves the Hubble tension, then it could affect the balance of the other cosmological parameters, in a way that might increase the number of bright galaxies that appear at early times. To test their theory, they incorporated a model of early dark energy (the same one that happens to resolve the Hubble tension) into an empirical galaxy formation framework to see how the earliest dark matter structures evolve and give rise to the first galaxies.
“What we show is, the skeletal structure of the early universe is altered in a subtle way where the amplitude of fluctuations goes up, and you get bigger halos, and brighter galaxies that are in place at earlier times, more so than in our more vanilla models,” Naidu says. “It means things were more abundant, and more clustered in the early universe.”
“A priori, I would not have expected the abundance of JWST’s early bright galaxies to have anything to do with early dark energy, but their observation that EDE pushes cosmological parameters in a direction that boosts the early-galaxy abundance is interesting,” says Marc Kamionkowski, professor of theoretical physics at Johns Hopkins University, who was not involved with the study. “I think more work will need to be done to establish a link between early galaxies and EDE, but regardless of how things turn out, it’s a clever — and hopefully ultimately fruitful — thing to try.”
“We demonstrated the potential of early dark energy as a unified solution to the two major issues faced by cosmology. This might be an evidence for its existence if the observational findings of JWST get further consolidated,” Vogelsberger concludes. “In the future, we can incorporate this into large cosmological simulations to see what detailed predictions we get.”
This research was supported, in part, by NASA and the National Science Foundation.
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Plant-derived secondary organic aerosols can act as mediators of plant-plant interactions
A new study published in Science reveals that plant-derived secondary organic aerosols (SOAs) can act as mediators of plant-plant interactions. This research was conducted through the cooperation of chemical ecologists, plant ecophysiologists and atmospheric physicists at the University of Eastern Finland.
The study showed that Scots pine seedlings, when damaged by large pine weevils, release VOCs that activate defences in nearby plants of the same species. Interestingly, the biological activity persisted after VOCs were oxidized to form SOAs. The results indicated that the elemental composition and quantity of SOAs likely determines their biological functions.
“A key novelty of the study is the finding that plants adopt subtly different defence strategies when receiving signals as VOCs or as SOAs, yet they exhibit similar degrees of resistance to herbivore feeding,” said Professor James Blande, head of the Environmental Ecology Research Group. This observation opens up the possibility that plants have sophisticated sensing systems that enable them to tailor their defences to information derived from different types of chemical cue.
“Considering the formation rate of SOAs from their precursor VOCs, their longer lifetime compared to VOCs, and the atmospheric air mass transport, we expect that the ecologically effective distance for interactions mediated by SOAs is longer than that for plant interactions mediated by VOCs,” said Professor Annele Virtanen, head of the Aerosol Physics Research Group. This could be interpreted as plants being able to detect cues representing close versus distant threats from herbivores.
The study is expected to open up a whole new complex research area to environmental ecologists and their collaborators, which could lead to new insights on the chemical cues structuring interactions between plants.
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Folded or cut, this lithium-sulfur battery keeps going
Most rechargeable batteries that power portable devices, such as toys, handheld vacuums and e-bikes, use lithium-ion technology. But these batteries can have short lifetimes and may catch fire when damaged. To address stability and safety issues, researchers reporting in ACS Energy Letters have designed a lithium-sulfur (Li-S) battery that features an improved iron sulfide cathode. One prototype remains highly stable over 300 charge-discharge cycles, and another provides power even after being folded or cut.
The team coated iron sulfide cathodes in different polymers and found in initial electrochemical performance tests that polyacrylic acid (PAA) performed best, retaining the electrode’s discharge capacity after 300 charge-discharge cycles. Next, the researchers incorporated a PAA-coated iron sulfide cathode into a prototype battery design, which also included a carbonate-based electrolyte, a lithium metal foil as an ion source, and a graphite-based anode. They produced and then tested both pouch cell and coin cell battery prototypes.
After more than 100 charge-discharge cycles, Wang and colleagues observed no substantial capacity decay in the pouch cell. Additional experiments showed that the pouch cell still worked after being folded and cut in half. The coin cell retained 72% of its capacity after 300 charge-discharge cycles. They next applied the polymer coating to cathodes made from other metals, creating lithium-molybdenum and lithium-vanadium batteries. These cells also had stable capacity over 300 charge-discharge cycles. Overall, the results indicate that coated cathodes could produce not only safer Li-S batteries with long lifespans, but also efficient batteries with other metal sulfides, according to Wang’s team.
The authors acknowledge funding from the National Natural Science Foundation of China; the Natural Science Foundation of Sichuan, China; and the Beijing National Laboratory for Condensed Matter Physics.
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