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New study supports stable mantle chemistry dating back to Earth’s early geologic history and over its prodigious evolution

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New study supports stable mantle chemistry dating back to Earth’s early geologic history and over its prodigious evolution


A new analysis of rocks thought to be at least 2.5 billion years old by researchers at the Smithsonian’s National Museum of Natural History helps clarify the chemical history of Earth’s mantle — the geologic layer beneath the planet’s crust. The findings hone scientists’ understanding of Earth’s earliest geologic processes, and they provide new evidence in a decades-long scientific debate about the geologic history of Earth. Specifically, the results provide evidence that the oxidation state of the vast majority of Earth’s mantle has remained stable through geologic time and has not undergone major transitions, contrary to what has been suggested previously by other researchers.

“This study tells us more about how this special place in which we live came to be the way it is, with its unique surface and interior that have allowed life and liquid water to exist,” said Elizabeth Cottrell, chair of the museum’s department of mineral sciences, curator of the National Rock Collection and co-author of the study. “It’s part of our story as humans because our origins all trace back to how Earth formed and how it has evolved.”

The study, published today in the journal Nature, centered on a group of rocks collected from the seafloor that possessed unusual geochemical properties. Namely, the rocks show evidence of having melted to an extreme degree with very low levels of oxidation; oxidation is when an atom or molecule loses one or more electrons in a chemical reaction. With the help of additional analyses and modeling, the researchers used the unique properties of these rocks to show that they likely date back to at least 2.5 billion years ago during the Archean Eon. Further, the findings show that the Earth’s mantle has overall retained a stable oxidation state since these rocks formed, in contrast to what other geologists have previously theorized.

“The ancient rocks we studied are 10,000 times less oxidized than typical modern mantle rocks, and we present evidence that this is because they melted deep in the Earth during the Archean, when the mantle was much hotter than it is today,” Cottrell said. “Other researchers have tried to explain the higher oxidation levels seen in rocks from today’s mantle by suggesting that an oxidation event or change has taken place between the Archean and today. Our evidence suggests that the difference in oxidation levels can simply be explained by the fact that Earth’s mantle has cooled over billions of years and is no longer hot enough to produce rocks with such low oxidation levels.”

The research team — including lead study author Suzanne Birner who completed a pre-doctoral fellowship at the National Museum of Natural History and is now an assistant professor at Berea College in Kentucky — began their investigation to understand the relationship between Earth’s solid mantle and modern seafloor volcanic rocks. The researchers started by studying a group of rocks that were dredged from the seafloor at two oceanic ridges where tectonic plates are spreading apart and the mantle is churning up to the surface and producing new crust.

The two places the studied rocks were collected from, the Gakkel Ridge near the North Pole and the Southwest Indian Ridge between Africa and Antarctica, are two of the slowest-spreading tectonic plate boundaries in the world. The slow pace of the spreading at these ocean ridges means that they are relatively quiet, volcanically speaking, compared to faster spreading ridges that are peppered with volcanoes such as the East Pacific Rise. This means that rocks collected from these slow-spreading ridges are more likely to be samples of the mantle itself.

When the team analyzed the mantle rocks they collected from these two ridges, they discovered they had strange chemical properties in common. First, the rocks had been melted to a much greater extent than is typical of Earth’s mantle today. Second, the rocks were much less oxidized than most other samples of Earth’s mantle.

To achieve such a high degree of melting, the researchers reasoned that the rocks must have melted deep in the Earth at very high temperatures. The only period of Earth’s geologic history known to include such high temperatures was between 2.5 and 4 billion years ago during the Archean Eon. Consequently, the researchers inferred that these mantle rocks may have melted during the Archean, when the inside of the planet was 360-540 degrees Fahrenheit (200-300 degrees Celsius) hotter than it is today.

Being so extremely melted would have protected these rocks from further melting that could have altered their chemical signature, allowing them to circulate in Earth’s mantle for billions of years without significantly changing their chemistry.

“This fact alone doesn’t prove anything,” Cottrell said. “But it opens the door to these samples being genuine geologic time capsules from the Archean.”

To explore the geochemical scenarios that might explain the low oxidation levels of the rocks collected at Gakkel Ridge and the Southwest Indian Ridge, the team applied multiple models to their measurements. The models revealed that the low oxidation levels they measured in their samples could have been caused by melting under extremely hot conditions deep in the Earth.

Both lines of evidence backed the interpretation that the rocks’ atypical properties represented a chemical signature from having melted deep in the Earth during the Archean, when the mantle could produce extremely high temperatures.

Previously, some geologists have interpreted mantle rocks with low oxidation levels as evidence that the Archean Earth’s mantle was less oxidized and that through some mechanism it has become more oxidized over time. Proposed oxidation mechanisms include a gradual increase in oxidation levels due to a loss of gasses to space, recycling of old seafloor by subduction and ongoing participation of Earth’s core in mantle geochemistry. But, to date, proponents of this view have not coalesced around any one explanation.

Instead, the new findings support the view that the oxidation level of Earth’s mantle has been largely steady for billions of years, and that the low oxidation seen in some samples of the mantle were created under geologic conditions the Earth can no longer produce because its mantle has since cooled. So, instead of some mechanism making Earth’s mantle more oxidized over billions of years, the new study argues that the high temperatures of the Archean made parts of the mantle less oxidized. Because Earth’s mantle has cooled since the Archean, it cannot produce rocks with super low oxidation levels anymore. Cottrell said the process of the planet’s mantle cooling provides a much simpler explanation: Earth simply does not make rocks like it used to.

Cottrell and her collaborators are now seeking to better understand the geochemical processes that shaped the Archean mantle rocks from the Gakkel Ridge and the Southwest Indian Ridge by simulating in the lab the extremely high pressures and temperatures found in the Archean.

This research contributes to the museum’s Our Unique Planet initiative. As a public-private research partnership, Our Unique Planet investigates what sets Earth apart from its cosmic neighbors by exploring the origins of the planet’s oceans and continents, as well as how minerals may have served as templates for life.

In addition to Birner and Cottrell, Fred Davis of the University of Minnesota Duluth and Jessica Warren of the University of Delaware were co-authors of the study.

The research was supported by the Smithsonian and the National Science Foundation.



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Early dark energy could resolve cosmology’s two biggest puzzles

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New study supports stable mantle chemistry dating back to Earth’s early geologic history and over its prodigious evolution


A new study by MIT physicists proposes that a mysterious force known as early dark energy could solve two of the biggest puzzles in cosmology and fill in some major gaps in our understanding of how the early universe evolved.

One puzzle in question is the “Hubble tension,” which refers to a mismatch in measurements of how fast the universe is expanding. The other involves observations of numerous early, bright galaxies that existed at a time when the early universe should have been much less populated.

Now, the MIT team has found that both puzzles could be resolved if the early universe had one extra, fleeting ingredient: early dark energy. Dark energy is an unknown form of energy that physicists suspect is driving the expansion of the universe today. Early dark energy is a similar, hypothetical phenomenon that may have made only a brief appearance, influencing the expansion of the universe in its first moments before disappearing entirely.

Some physicists have suspected that early dark energy could be the key to solving the Hubble tension, as the mysterious force could accelerate the early expansion of the universe by an amount that would resolve the measurement mismatch.

The MIT researchers have now found that early dark energy could also explain the baffling number of bright galaxies that astronomers have observed in the early universe. In their new study, reported in the Monthly Notices of the Royal Astronomical Society, the team modeled the formation of galaxies in the universe’s first few hundred million years. When they incorporated a dark energy component only in that earliest sliver of time, they found the number of galaxies that arose from the primordial environment bloomed to fit astronomers’ observations.

You have these two looming open-ended puzzles,” says study co-author Rohan Naidu, a postdoc in MIT’s Kavli Institute for Astrophysics and Space Research. “We find that in fact, early dark energy is a very elegant and sparse solution to two of the most pressing problems in cosmology.”

The study’s co-authors include lead author and Kavli postdoc Xuejian (Jacob) Shen, and MIT professor of physics Mark Vogelsberger, along with Michael Boylan-Kolchin at the University of Texas at Austin, and Sandro Tacchella at the University of Cambridge.

Big city lights

Based on standard cosmological and galaxy formation models, the universe should have taken its time spinning up the first galaxies. It would have taken billions of years for primordial gas to coalesce into galaxies as large and bright as the Milky Way.

But in 2023, NASA’s James Webb Space Telescope (JWST) made a startling observation. With an ability to peer farther back in time than any observatory to date, the telescope uncovered a surprising number of bright galaxies as large as the modern Milky Way within the first 500 million years, when the universe was just 3 percent of its current age.

“The bright galaxies that JWST saw would be like seeing a clustering of lights around big cities, whereas theory predicts something like the light around more rural settings like Yellowstone National Park,” Shen says. “And we don’t expect that clustering of light so early on.”

For physicists, the observations imply that there is either something fundamentally wrong with the physics underlying the models or a missing ingredient in the early universe that scientists have not accounted for. The MIT team explored the possibility of the latter, and whether the missing ingredient might be early dark energy.

Physicists have proposed that early dark energy is a sort of antigravitational force that is turned on only at very early times. This force would counteract gravity’s inward pull and accelerate the early expansion of the universe, in a way that would resolve the mismatch in measurements. Early dark energy, therefore, is considered the most likely solution to the Hubble tension.

Galaxy skeleton

The MIT team explored whether early dark energy could also be the key to explaining the unexpected population of large, bright galaxies detected by JWST. In their new study, the physicists considered how early dark energy might affect the early structure of the universe that gave rise to the first galaxies. They focused on the formation of dark matter halos — regions of space where gravity happens to be stronger, and where matter begins to accumulate.

“We believe that dark matter halos are the invisible skeleton of the universe,” Shen explains. “Dark matter structures form first, and then galaxies form within these structures. So, we expect the number of bright galaxies should be proportional to the number of big dark matter halos.”

The team developed an empirical framework for early galaxy formation, which predicts the number, luminosity, and size of galaxies that should form in the early universe, given some measures of “cosmological parameters.” Cosmological parameters are the basic ingredients, or mathematical terms, that describe the evolution of the universe.

Physicists have determined that there are at least six main cosmological parameters, one of which is the Hubble constant — a term that describes the universe’s rate of expansion. Other parameters describe density fluctuations in the primordial soup, immediately after the Big Bang, from which dark matter halos eventually form.

The MIT team reasoned that if early dark energy affects the universe’s early expansion rate, in a way that resolves the Hubble tension, then it could affect the balance of the other cosmological parameters, in a way that might increase the number of bright galaxies that appear at early times. To test their theory, they incorporated a model of early dark energy (the same one that happens to resolve the Hubble tension) into an empirical galaxy formation framework to see how the earliest dark matter structures evolve and give rise to the first galaxies.

“What we show is, the skeletal structure of the early universe is altered in a subtle way where the amplitude of fluctuations goes up, and you get bigger halos, and brighter galaxies that are in place at earlier times, more so than in our more vanilla models,” Naidu says. “It means things were more abundant, and more clustered in the early universe.”

“A priori, I would not have expected the abundance of JWST’s early bright galaxies to have anything to do with early dark energy, but their observation that EDE pushes cosmological parameters in a direction that boosts the early-galaxy abundance is interesting,” says Marc Kamionkowski, professor of theoretical physics at Johns Hopkins University, who was not involved with the study. “I think more work will need to be done to establish a link between early galaxies and EDE, but regardless of how things turn out, it’s a clever — and hopefully ultimately fruitful — thing to try.”

We demonstrated the potential of early dark energy as a unified solution to the two major issues faced by cosmology. This might be an evidence for its existence if the observational findings of JWST get further consolidated,” Vogelsberger concludes. “In the future, we can incorporate this into large cosmological simulations to see what detailed predictions we get.”

This research was supported, in part, by NASA and the National Science Foundation.



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Plant-derived secondary organic aerosols can act as mediators of plant-plant interactions

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New study supports stable mantle chemistry dating back to Earth’s early geologic history and over its prodigious evolution


A new study published in Science reveals that plant-derived secondary organic aerosols (SOAs) can act as mediators of plant-plant interactions. This research was conducted through the cooperation of chemical ecologists, plant ecophysiologists and atmospheric physicists at the University of Eastern Finland.

It is well known that plants release volatile organic compounds (VOCs) into the atmosphere when damaged by herbivores. These VOCs play a crucial role in plant-plant interactions, whereby undamaged plants may detect warning signals from their damaged neighbours and prepare their defences. “Reactive plant VOCs undergo oxidative chemical reactions, resulting in the formation of secondary organic aerosols (SOAs). We wondered whether the ecological functions mediated by VOCs persist after they are oxidated to form SOAs,” said Dr. Hao Yu, formerly a PhD student at UEF, but now at the University of Bern.

The study showed that Scots pine seedlings, when damaged by large pine weevils, release VOCs that activate defences in nearby plants of the same species. Interestingly, the biological activity persisted after VOCs were oxidized to form SOAs. The results indicated that the elemental composition and quantity of SOAs likely determines their biological functions.

“A key novelty of the study is the finding that plants adopt subtly different defence strategies when receiving signals as VOCs or as SOAs, yet they exhibit similar degrees of resistance to herbivore feeding,” said Professor James Blande, head of the Environmental Ecology Research Group. This observation opens up the possibility that plants have sophisticated sensing systems that enable them to tailor their defences to information derived from different types of chemical cue.

“Considering the formation rate of SOAs from their precursor VOCs, their longer lifetime compared to VOCs, and the atmospheric air mass transport, we expect that the ecologically effective distance for interactions mediated by SOAs is longer than that for plant interactions mediated by VOCs,” said Professor Annele Virtanen, head of the Aerosol Physics Research Group. This could be interpreted as plants being able to detect cues representing close versus distant threats from herbivores.

The study is expected to open up a whole new complex research area to environmental ecologists and their collaborators, which could lead to new insights on the chemical cues structuring interactions between plants.



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Folded or cut, this lithium-sulfur battery keeps going

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New study supports stable mantle chemistry dating back to Earth’s early geologic history and over its prodigious evolution


Most rechargeable batteries that power portable devices, such as toys, handheld vacuums and e-bikes, use lithium-ion technology. But these batteries can have short lifetimes and may catch fire when damaged. To address stability and safety issues, researchers reporting in ACS Energy Letters have designed a lithium-sulfur (Li-S) battery that features an improved iron sulfide cathode. One prototype remains highly stable over 300 charge-discharge cycles, and another provides power even after being folded or cut.

Sulfur has been suggested as a material for lithium-ion batteries because of its low cost and potential to hold more energy than lithium-metal oxides and other materials used in traditional ion-based versions. To make Li-S batteries stable at high temperatures, researchers have previously proposed using a carbonate-based electrolyte to separate the two electrodes (an iron sulfide cathode and a lithium metal-containing anode). However, as the sulfide in the cathode dissolves into the electrolyte, it forms an impenetrable precipitate, causing the cell to quickly lose capacity. Liping Wang and colleagues wondered if they could add a layer between the cathode and electrolyte to reduce this corrosion without reducing functionality and rechargeability.

The team coated iron sulfide cathodes in different polymers and found in initial electrochemical performance tests that polyacrylic acid (PAA) performed best, retaining the electrode’s discharge capacity after 300 charge-discharge cycles. Next, the researchers incorporated a PAA-coated iron sulfide cathode into a prototype battery design, which also included a carbonate-based electrolyte, a lithium metal foil as an ion source, and a graphite-based anode. They produced and then tested both pouch cell and coin cell battery prototypes.

After more than 100 charge-discharge cycles, Wang and colleagues observed no substantial capacity decay in the pouch cell. Additional experiments showed that the pouch cell still worked after being folded and cut in half. The coin cell retained 72% of its capacity after 300 charge-discharge cycles. They next applied the polymer coating to cathodes made from other metals, creating lithium-molybdenum and lithium-vanadium batteries. These cells also had stable capacity over 300 charge-discharge cycles. Overall, the results indicate that coated cathodes could produce not only safer Li-S batteries with long lifespans, but also efficient batteries with other metal sulfides, according to Wang’s team.

The authors acknowledge funding from the National Natural Science Foundation of China; the Natural Science Foundation of Sichuan, China; and the Beijing National Laboratory for Condensed Matter Physics.



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