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Surprising phosphate finding in NASA’s OSIRIS-REx asteroid sample
Early analysis of the asteroid Bennu sample returned by NASA’s OSIRIS-REx mission has revealed dust rich in carbon, nitrogen, and organic compounds, all of which are essential components for life as we know it. Dominated by clay minerals, particularly serpentine, the sample mirrors the type of rock found at mid-ocean ridges on Earth.
While a similar phosphate was found in the asteroid Ryugu sample delivered by JAXA’s (Japan Aerospace Exploration Agency) Hayabusa2 mission in 2020, the magnesium-sodium phosphate detected in the Bennu sample stands out for its purity (that is, the lack of other materials included in the mineral) and the size of its grains, unprecedented in any meteorite sample.
Scientists have eagerly awaited the opportunity to dig into the 4.3-ounce (121.6-gram) pristine asteroid Bennu sample collected by NASA’s OSIRIS-REx (Origins, Spectral Interpretation, Resource Identification, and Security — Regolith Explorer) mission since it was delivered to Earth last fall. They hoped the material would hold secrets of the solar system’s past and the prebiotic chemistry that might have led to the origin of life on Earth. An early analysis of the Bennu sample, published June 26 in Meteoritics & Planetary Science, demonstrates this excitement was warranted.
The OSIRIS-REx Sample Analysis Team found that Bennu contains the original ingredients that formed our solar system. The asteroid’s dust is rich in carbon and nitrogen, as well as organic compounds, all of which are essential components for life as we know it. The sample also contains magnesium-sodium phosphate, which was a surprise to the research team, because it wasn’t seen in the remote sensing data collected by the spacecraft at Bennu. Its presence in the sample hints that the asteroid could have splintered off from a long-gone, tiny, primitive ocean world.
A Phosphate Surprise
Analysis of the Bennu sample unveiled intriguing insights into the asteroid’s composition. Dominated by clay minerals, particularly serpentine, the sample mirrors the type of rock found at mid-ocean ridges on Earth, where material from the mantle, the layer beneath Earth’s crust, encounters water.
This interaction doesn’t just result in clay formation; it also gives rise to a variety of minerals like carbonates, iron oxides, and iron sulfides. But the most unexpected discovery is the presence of water-soluble phosphates. These compounds are components of biochemistry for all known life on Earth today.
While a similar phosphate was found in the asteroid Ryugu sample delivered by JAXA’s (Japan Aerospace Exploration Agency) Hayabusa2 mission in 2020, the magnesium-sodium phosphate detected in the Bennu sample stands out for its purity — that is, the lack of other materials in the mineral — and the size of its grains, unprecedented in any meteorite sample.
The finding of magnesium-sodium phosphates in the Bennu sample raises questions about the geochemical processes that concentrated these elements and provides valuable clues about Bennu’s historic conditions.
“The presence and state of phosphates, along with other elements and compounds on Bennu, suggest a watery past for the asteroid,” said Dante Lauretta, co-lead author of the paper and principal investigator for OSIRIS-REx at the University of Arizona, Tucson. “Bennu potentially could have once been part of a wetter world. Although, this hypothesis requires further investigation.”
“OSIRIS-REx gave us exactly what we hoped: a large pristine asteroid sample rich in nitrogen and carbon from a formerly wet world,” said Jason Dworkin, a co-author on the paper and the OSIRIS-REx project scientist at NASA’s Goddard Space Flight Center in Greenbelt, Maryland.
From a Young Solar System
Despite its possible history of interaction with water, Bennu remains a chemically primitive asteroid, with elemental proportions closely resembling those of the Sun.
“The sample we returned is the largest reservoir of unaltered asteroid material on Earth right now,” said Lauretta.
This composition offers a glimpse into the early days of our solar system, over 4.5 billion years ago. These rocks have retained their original state, having neither melted nor resolidified since their inception, affirming their ancient origins.
Hints at Life’s Building Blocks
The team has confirmed the asteroid is rich in carbon and nitrogen. These elements are crucial in understanding the environments where Bennu’s materials originated and the chemical processes that transformed simple elements into complex molecules, potentially laying the groundwork for life on Earth.
“These findings underscore the importance of collecting and studying material from asteroids like Bennu — especially low-density material that would typically burn up upon entering Earth’s atmosphere,” said Lauretta. “This material holds the key to unraveling the intricate processes of solar system formation and the prebiotic chemistry that could have contributed to life emerging on Earth.”
What’s Next
Dozens more labs in the United States and around the world will receive portions of the Bennu sample from NASA’s Johnson Space Center in Houston in the coming months, and many more scientific papers describing analyses of the Bennu sample are expected in the next few years from the OSIRIS-REx Sample Analysis Team.
“The Bennu samples are tantalizingly beautiful extraterrestrial rocks,” said Harold Connolly, co-lead author on the paper and OSIRIS-REx mission sample scientist at Rowan University in Glassboro, New Jersey. “Each week, analysis by the OSIRIS-REx Sample Analysis Team provides new and sometimes surprising findings that are helping place important constraints on the origin and evolution of Earth-like planets.”
Launched on Sept. 8, 2016, the OSIRIS-REx spacecraft traveled to near-Earth asteroid Bennu and collected a sample of rocks and dust from the surface. OSIRIS-REx, the first U.S. mission to collect a sample from an asteroid, delivered the sample to Earth on Sept. 24, 2023.
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Early dark energy could resolve cosmology’s two biggest puzzles
A new study by MIT physicists proposes that a mysterious force known as early dark energy could solve two of the biggest puzzles in cosmology and fill in some major gaps in our understanding of how the early universe evolved.
Now, the MIT team has found that both puzzles could be resolved if the early universe had one extra, fleeting ingredient: early dark energy. Dark energy is an unknown form of energy that physicists suspect is driving the expansion of the universe today. Early dark energy is a similar, hypothetical phenomenon that may have made only a brief appearance, influencing the expansion of the universe in its first moments before disappearing entirely.
Some physicists have suspected that early dark energy could be the key to solving the Hubble tension, as the mysterious force could accelerate the early expansion of the universe by an amount that would resolve the measurement mismatch.
The MIT researchers have now found that early dark energy could also explain the baffling number of bright galaxies that astronomers have observed in the early universe. In their new study, reported in the Monthly Notices of the Royal Astronomical Society, the team modeled the formation of galaxies in the universe’s first few hundred million years. When they incorporated a dark energy component only in that earliest sliver of time, they found the number of galaxies that arose from the primordial environment bloomed to fit astronomers’ observations.
“You have these two looming open-ended puzzles,” says study co-author Rohan Naidu, a postdoc in MIT’s Kavli Institute for Astrophysics and Space Research. “We find that in fact, early dark energy is a very elegant and sparse solution to two of the most pressing problems in cosmology.”
The study’s co-authors include lead author and Kavli postdoc Xuejian (Jacob) Shen, and MIT professor of physics Mark Vogelsberger, along with Michael Boylan-Kolchin at the University of Texas at Austin, and Sandro Tacchella at the University of Cambridge.
Big city lights
Based on standard cosmological and galaxy formation models, the universe should have taken its time spinning up the first galaxies. It would have taken billions of years for primordial gas to coalesce into galaxies as large and bright as the Milky Way.
But in 2023, NASA’s James Webb Space Telescope (JWST) made a startling observation. With an ability to peer farther back in time than any observatory to date, the telescope uncovered a surprising number of bright galaxies as large as the modern Milky Way within the first 500 million years, when the universe was just 3 percent of its current age.
“The bright galaxies that JWST saw would be like seeing a clustering of lights around big cities, whereas theory predicts something like the light around more rural settings like Yellowstone National Park,” Shen says. “And we don’t expect that clustering of light so early on.”
For physicists, the observations imply that there is either something fundamentally wrong with the physics underlying the models or a missing ingredient in the early universe that scientists have not accounted for. The MIT team explored the possibility of the latter, and whether the missing ingredient might be early dark energy.
Physicists have proposed that early dark energy is a sort of antigravitational force that is turned on only at very early times. This force would counteract gravity’s inward pull and accelerate the early expansion of the universe, in a way that would resolve the mismatch in measurements. Early dark energy, therefore, is considered the most likely solution to the Hubble tension.
Galaxy skeleton
The MIT team explored whether early dark energy could also be the key to explaining the unexpected population of large, bright galaxies detected by JWST. In their new study, the physicists considered how early dark energy might affect the early structure of the universe that gave rise to the first galaxies. They focused on the formation of dark matter halos — regions of space where gravity happens to be stronger, and where matter begins to accumulate.
“We believe that dark matter halos are the invisible skeleton of the universe,” Shen explains. “Dark matter structures form first, and then galaxies form within these structures. So, we expect the number of bright galaxies should be proportional to the number of big dark matter halos.”
The team developed an empirical framework for early galaxy formation, which predicts the number, luminosity, and size of galaxies that should form in the early universe, given some measures of “cosmological parameters.” Cosmological parameters are the basic ingredients, or mathematical terms, that describe the evolution of the universe.
Physicists have determined that there are at least six main cosmological parameters, one of which is the Hubble constant — a term that describes the universe’s rate of expansion. Other parameters describe density fluctuations in the primordial soup, immediately after the Big Bang, from which dark matter halos eventually form.
The MIT team reasoned that if early dark energy affects the universe’s early expansion rate, in a way that resolves the Hubble tension, then it could affect the balance of the other cosmological parameters, in a way that might increase the number of bright galaxies that appear at early times. To test their theory, they incorporated a model of early dark energy (the same one that happens to resolve the Hubble tension) into an empirical galaxy formation framework to see how the earliest dark matter structures evolve and give rise to the first galaxies.
“What we show is, the skeletal structure of the early universe is altered in a subtle way where the amplitude of fluctuations goes up, and you get bigger halos, and brighter galaxies that are in place at earlier times, more so than in our more vanilla models,” Naidu says. “It means things were more abundant, and more clustered in the early universe.”
“A priori, I would not have expected the abundance of JWST’s early bright galaxies to have anything to do with early dark energy, but their observation that EDE pushes cosmological parameters in a direction that boosts the early-galaxy abundance is interesting,” says Marc Kamionkowski, professor of theoretical physics at Johns Hopkins University, who was not involved with the study. “I think more work will need to be done to establish a link between early galaxies and EDE, but regardless of how things turn out, it’s a clever — and hopefully ultimately fruitful — thing to try.”
“We demonstrated the potential of early dark energy as a unified solution to the two major issues faced by cosmology. This might be an evidence for its existence if the observational findings of JWST get further consolidated,” Vogelsberger concludes. “In the future, we can incorporate this into large cosmological simulations to see what detailed predictions we get.”
This research was supported, in part, by NASA and the National Science Foundation.
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Plant-derived secondary organic aerosols can act as mediators of plant-plant interactions
A new study published in Science reveals that plant-derived secondary organic aerosols (SOAs) can act as mediators of plant-plant interactions. This research was conducted through the cooperation of chemical ecologists, plant ecophysiologists and atmospheric physicists at the University of Eastern Finland.
The study showed that Scots pine seedlings, when damaged by large pine weevils, release VOCs that activate defences in nearby plants of the same species. Interestingly, the biological activity persisted after VOCs were oxidized to form SOAs. The results indicated that the elemental composition and quantity of SOAs likely determines their biological functions.
“A key novelty of the study is the finding that plants adopt subtly different defence strategies when receiving signals as VOCs or as SOAs, yet they exhibit similar degrees of resistance to herbivore feeding,” said Professor James Blande, head of the Environmental Ecology Research Group. This observation opens up the possibility that plants have sophisticated sensing systems that enable them to tailor their defences to information derived from different types of chemical cue.
“Considering the formation rate of SOAs from their precursor VOCs, their longer lifetime compared to VOCs, and the atmospheric air mass transport, we expect that the ecologically effective distance for interactions mediated by SOAs is longer than that for plant interactions mediated by VOCs,” said Professor Annele Virtanen, head of the Aerosol Physics Research Group. This could be interpreted as plants being able to detect cues representing close versus distant threats from herbivores.
The study is expected to open up a whole new complex research area to environmental ecologists and their collaborators, which could lead to new insights on the chemical cues structuring interactions between plants.
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Folded or cut, this lithium-sulfur battery keeps going
Most rechargeable batteries that power portable devices, such as toys, handheld vacuums and e-bikes, use lithium-ion technology. But these batteries can have short lifetimes and may catch fire when damaged. To address stability and safety issues, researchers reporting in ACS Energy Letters have designed a lithium-sulfur (Li-S) battery that features an improved iron sulfide cathode. One prototype remains highly stable over 300 charge-discharge cycles, and another provides power even after being folded or cut.
The team coated iron sulfide cathodes in different polymers and found in initial electrochemical performance tests that polyacrylic acid (PAA) performed best, retaining the electrode’s discharge capacity after 300 charge-discharge cycles. Next, the researchers incorporated a PAA-coated iron sulfide cathode into a prototype battery design, which also included a carbonate-based electrolyte, a lithium metal foil as an ion source, and a graphite-based anode. They produced and then tested both pouch cell and coin cell battery prototypes.
After more than 100 charge-discharge cycles, Wang and colleagues observed no substantial capacity decay in the pouch cell. Additional experiments showed that the pouch cell still worked after being folded and cut in half. The coin cell retained 72% of its capacity after 300 charge-discharge cycles. They next applied the polymer coating to cathodes made from other metals, creating lithium-molybdenum and lithium-vanadium batteries. These cells also had stable capacity over 300 charge-discharge cycles. Overall, the results indicate that coated cathodes could produce not only safer Li-S batteries with long lifespans, but also efficient batteries with other metal sulfides, according to Wang’s team.
The authors acknowledge funding from the National Natural Science Foundation of China; the Natural Science Foundation of Sichuan, China; and the Beijing National Laboratory for Condensed Matter Physics.
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