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The first battery prototype using hemoglobin is developed

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The first battery prototype using hemoglobin is developed


The first battery prototype using hemoglobin is developed

by Staff Writers for UCO News

Cordoba, Spain (SPX) Jan 11, 2024






A team with the Chemical Institute for Energy and the Environment (IQUEMA) at the University of Cordoba has come up with a battery that uses hemoglobin as an electrochemical reaction facilitator, functioning for around 20-30 days.

Hemoglobin is a protein present in red blood cells and is responsible for conveying oxygen from the lungs to the different tissues of the body (and then transferring carbon dioxide the other way around). It has a very high affinity for oxygen and is fundamental for life, but, what if it were also a key element for a type of electrochemical device in which oxygen also plays an important role, such as zinc-air batteries?



This is what the Physical Chemistry (FQM-204) and Inorganic Chemistry (FQM-175) groups at the University of Cordoba (UCO) wanted to verify and develop, together with a team from the Polytechnic University of Cartagena, after study by the University of Oxford and a Final Degree Project at the UCO demonstrated that hemoglobin featured promising properties for the reduction and oxidation (redox) process by which energy is generated in this type of system. Thus, the research team developed, through a Proof of Concept project, the first biocompatible battery (which is not harmful to the body) using hemoglobin in the electrochemical reaction that transforms chemical energy into electrical energy.



Using zinc-air batteries, one of the most sustainable alternatives to those that currently dominate the market (lithium-ion batteries), hemoglobin would function as a catalyst in such batteries. That is, it is a protein that is responsible for facilitating the electrochemical reaction, called the Oxygen Reduction Reaction (ORR), causing, after the air enters the battery, oxygen to be reduced and transformed into water in one of the parts of the battery (the cathode or positive pole), releasing electrons that pass to the other part of the battery (the anode or negative pole), where zinc oxidation occurs.



As UCO researcher Manuel Cano Luna explains: “to be a good catalyst in the oxygen reduction reaction, the catalyst has to have two properties: it needs to quickly absorb oxygen molecules, and form water molecules relatively easily. And hemoglobin met those requirements.” In fact, through this process, the team managed to get their prototype biocompatible battery to work with 0.165 milligrams of hemoglobin for between 20 and 30 days.



In addition to strong performance, the battery prototype they have developed boasts other advantages. First of all, zinc-air batteries are more sustainable and can withstand adverse atmospheric conditions, unlike other batteries affected by humidity and requiring an inert atmosphere for their manufacture. Secondly, as Cano Luna argues, “the use of hemoglobin as a biocompatible catalyst is quite promising as regards the use of this type of battery in devices that are integrated into the human body”, such as pacemakers. In fact, the battery operates at pH 7.4, which is a pH similar to that of blood. In addition, since hemoglobin is present in almost all mammals, protein of animal origin could also be used.



The battery they have developed has some room for improvement, however. The main one is that it is a primary battery, so it only discharges electrical energy. Also, it is not rechargeable. Therefore, the team is already taking the next steps to find another biological protein that can transform water into oxygen and, thus, recharge the battery. In addition, the batteries would only work in the presence of oxygen, so they could not be used in space.



The study, published in the journal Energy and Fuels, opens the door to new functional alternatives for batteries in a context in which more and more mobile devices are expected, and in which there is a rising commitment to renewable energies, such that it is necessary to have devices that store excess electrical energy in the form of chemical energy. Most importantly, the most common batteries today, lithium-ion, are saddled with the problems of lithium’s scarcity and its environmental impact as hazardous waste.



Research Report:Human Hemoglobin-Based Zinc-Air Battery in a Neutral Electrolyte



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Bolivia announces $1 bn deal with China to build lithium plants

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Bolivia announces  bn deal with China to build lithium plants


Bolivia announces $1 bn deal with China to build lithium plants

by AFP Staff Writers

La Paz (AFP) Nov 27, 2024






Bolivia said Tuesday it had signed a $1 billion deal with China’s CBC, a subsidiary of the world’s largest lithium battery producer CATL, to build two lithium carbonate production plants in the country’s southwest.

Bolivia’s state-owned Bolivia Lithium Deposits (YLB) said the plants — one with an annual capacity of 10,000 tons of lithium carbonate and the other of 25,000 – would be situated in the vast Uyuni salt flats.

Lithium, nicknamed “white gold,” is a key component in the production of batteries for electric vehicles and mobile phones.

Bolivia claims to have the world’s largest lithium deposits.

President Luis Arce, who presided over Tuesday’s signing ceremony, said it paved the way for Bolivia to become “a very important player in determining the international price of lithium.”

The deal follows an earlier agreement reached last year between Russia’s Uranium One Group and YLB to build a $970 million lithium extraction facility, also in Uyuni.

Both deals have yet to be approved by Bolivia’s parliament.

Arce announced that negotiations were underway with China’s Citic Guoan Group for a third contract.

“We hope to close that deal as soon as possible,” he said.

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The future of AI with solar-powered synaptic devices

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The future of AI with solar-powered synaptic devices


The future of AI with solar-powered synaptic devices

by Riko Seibo

Tokyo, Japan (SPX) Nov 26, 2024






Artificial intelligence (AI) is increasingly relied upon for predicting critical events such as heart attacks, natural disasters, and infrastructure failures. These applications demand technologies capable of rapidly processing data. One such promising approach is reservoir computing, particularly physical reservoir computing (PRC), known for its efficiency in handling time-series data with minimal power consumption. Optoelectronic artificial synapses in PRC, mimicking human neural synaptic structures, are poised to enable advanced real-time data processing and recognition akin to the human visual system.

Existing self-powered optoelectronic synaptic devices, however, struggle to process time-series data across diverse timescales, which is essential for applications in environmental monitoring, infrastructure maintenance, and healthcare.



Addressing this challenge, researchers at Tokyo University of Science (TUS), led by Associate Professor Takashi Ikuno and including Hiroaki Komatsu and Norika Hosoda, have developed an innovative self-powered dye-sensitized solar cell-based optoelectronic photopolymeric human synapse. This groundbreaking device, featuring a controllable time constant based on input light intensity, represents a major advancement in the field. The study, published on October 28, 2024, in ‘ACS Applied Materials and Interfaces’, highlights the potential of this technology.



Dr. Ikuno explained, “To process time-series input optical data with various time scales, it is essential to fabricate devices according to the desired time scale. Inspired by the afterimage phenomenon of the eye, we came up with a novel optoelectronic human synaptic device that can serve as a computational framework for power-saving edge AI optical sensors.”



The new device integrates squarylium derivative-based dyes, incorporating optical input, AI computation, analog output, and power supply at the material level. It demonstrates synaptic plasticity, exhibiting features such as paired-pulse facilitation and depression in response to light intensity. The device achieves high computational performance in time-series data processing tasks while maintaining low power consumption, regardless of the input light pulse width.



Remarkably, the device achieved over 90% accuracy in classifying human movements, including bending, jumping, running, and walking, when used as the reservoir layer of PRC. Its power consumption is only 1% of that required by traditional systems, significantly reducing carbon emissions. Dr. Ikuno emphasized, “We have demonstrated for the first time in the world that the developed device can operate with very low power consumption and yet identify human motion with a high accuracy rate.”



This innovation holds significant promise for edge AI applications, including surveillance cameras, automotive sensors, and health monitoring systems. “This invention can be used as a massively popular edge AI optical sensor that can be attached to any object or person,” noted Dr. Ikuno. He further highlighted its potential to improve vehicle energy efficiency and reduce costs in standalone smartwatches and medical devices.



The novel solar cell-based device could redefine energy-efficient edge AI sensors across various applications, marking a significant leap forward in both technology and sustainability.



Research Report:Self-Powered Dye-Sensitized Solar-Cell-Based Synaptic Devices for Multi-Scale Time-Series Data Processing in Physical Reservoir Computing


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Decarbonizing heavy industry with thermal batteries

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Decarbonizing heavy industry with thermal batteries


Decarbonizing heavy industry with thermal batteries

by Zach Winn | MIT News

Boston MA (SPX) Nov 27, 2024






Whether you’re manufacturing cement, steel, chemicals, or paper, you need a large amount of heat. Almost without exception, manufacturers around the world create that heat by burning fossil fuels.

In an effort to clean up the industrial sector, some startups are changing manufacturing processes for specific materials. Some are even changing the materials themselves. Daniel Stack SM ’17, PhD ’21 is trying to address industrial emissions across the board by replacing the heat source.



Since coming to MIT in 2014, Stack has worked to develop thermal batteries that use electricity to heat up a conductive version of ceramic firebricks, which have been used as heat stores and insulators for centuries. In 2021, Stack co-founded Electrified Thermal Solutions, which has since demonstrated that its firebricks can store heat efficiently for hours and discharge it by heating air or gas up to 3,272 degrees Fahrenheit – hot enough to power the most demanding industrial applications.



Achieving temperatures north of 3,000 F represents a breakthrough for the electric heating industry, as it enables some of the world’s hardest-to-decarbonize sectors to utilize renewable energy for the first time. It also unlocks a new, low-cost model for using electricity when it’s at its cheapest and cleanest.



“We have a global perspective at Electrified Thermal, but in the U.S. over the last five years, we’ve seen an incredible opportunity emerge in energy prices that favors flexible offtake of electricity,” Stack says. “Throughout the middle of the country, especially in the wind belt, electricity prices in many places are negative for more than 20 percent of the year, and the trend toward decreasing electricity pricing during off-peak hours is a nationwide phenomenon. Technologies like our Joule Hive Thermal Battery will enable us to access this inexpensive, clean electricity and compete head to head with fossil fuels on price for industrial heating needs, without even factoring in the positive climate impact.”



A new approach to an old technology

Stack’s research plans changed quickly when he joined MIT’s Department of Nuclear Science and Engineering as a master’s student in 2014.



“I went to MIT excited to work on the next generation of nuclear reactors, but what I focused on almost from day one was how to heat up bricks,” Stack says. “It wasn’t what I expected, but when I talked to my advisor, [Principal Research Scientist] Charles Forsberg, about energy storage and why it was valuable to not just nuclear power but the entire energy transition, I realized there was no project I would rather work on.”



Firebricks are ubiquitous, inexpensive clay bricks that have been used for millennia in fireplaces and ovens. In 2017, Forsberg and Stack co-authored a paper showing firebricks’ potential to store heat from renewable resources, but the system still used electric resistance heaters – like the metal coils in toasters and space heaters – which limited its temperature output.



For his doctoral work, Stack worked with Forsberg to make firebricks that were electrically conductive, replacing the resistance heaters so the bricks produced the heat directly.



“Electric heaters are your biggest limiter: They burn out too fast, they break down, they don’t get hot enough,” Stack explains. “The idea was to skip the heaters because firebricks themselves are really cheap, abundant materials that can go to flame-like temperatures and hang out there for days.”



Forsberg and Stacks were able to create conductive firebricks by tweaking the chemical composition of traditional firebricks. Electrified Thermal’s bricks are 98 percent similar to existing firebricks and are produced using the same processes, allowing existing manufacturers to make them inexpensively.



Toward the end of his PhD program, Stack realized the invention could be commercialized. He started taking classes at the MIT Sloan School of Management and spending time at the Martin Trust Center for MIT Entrepreneurship. He also entered the StartMIT program and the I-Corps program, and received support from the U.S. Department of Energy and MIT’s Venture Mentoring Service (VMS).



“Through the Boston ecosystem, the MIT ecosystem, and with help from the Department of Energy, we were able to launch this from the lab at MIT,” Stack says. “What we spun out was an electrically conductive firebrick, or what we refer to as an e-Brick.”



Electrified Thermal contains its firebrick arrays in insulated, off-the-shelf metal boxes. Although the system is highly configurable depending on the end use, the company’s standard system can collect and release about 5 megawatts of energy and store about 25 megawatt-hours.



The company has demonstrated its system’s ability to produce high temperatures and has been cycling its system at its headquarters in Medford, Massachusetts. That work has collectively earned Electrified Thermal $40 million from various the Department of Energy offices to scale the technology and work with manufacturers.



“Compared to other electric heating, we can run hotter and last longer than any other solution on the market,” Stack says. “That means replacing fossil fuels at a lot of industrial sites that couldn’t otherwise decarbonize.”



Scaling to solve a global problem

Electrified Thermal is engaging with hundreds of industrial companies, including manufacturers of cement, steel, glass, basic and specialty chemicals, food and beverage, and pulp and paper.



“The industrial heating challenge affects everyone under the sun,” Stack says. “They all have fundamentally the same problem, which is getting their heat in a way that is affordable and zero carbon for the energy transition.”



The company is currently building a megawatt-scale commercial version of its system, which it expects to be operational in the next seven months.



“Next year will be a huge proof point to the industry,” Stack says. “We’ll be using the commercial system to showcase a variety of operating points that customers need to see, and we’re hoping to be running systems on customer sites by the end of the year. It’ll be a huge achievement and a first for electric heating because no other solution in the market can put out the kind of temperatures that we can put out.”



By working with manufacturers to produce its firebricks and casings, Electrified Thermal hopes to be able to deploy its systems rapidly and at low cost across a massive industry.



“From the very beginning, we engineered these e-bricks to be rapidly scalable and rapidly producible within existing supply chains and manufacturing processes,” Stack says. “If you want to decarbonize heavy industry, there will be no cheaper way than turning electricity into heat from zero-carbon electricity assets. We’re seeking to be the premier technology that unlocks those capabilities, with double digit percentages of global energy flowing through our system as we accomplish the energy transition.”


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