Solar Energy

Air Force awards UToledo $12.5 million to develop space-based solar energy sheets

Published

4 years ago

February 17, 2021

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Air Force awards UToledo .5 million to develop space-based solar energy sheets

The military is adding fuel to the momentum of physicists at The University of Toledo who are advancing new frontiers in thin-film, highly efficient, low-cost photovoltaic technology to ensure a clean energy future.

The U.S. Air Force awarded UToledo $12.5 million to develop photovoltaic energy sheets that would live in space and harvest solar energy to transmit power wirelessly to Earth-based receivers or to other orbital or aerial instrumentation, such as communications satellites.

UToledo physicists will develop flexible solar cell sheets, each roughly the size of a piece of paper, that can be assembled and interconnected into much larger structures.

Although UToledo’s focus does not include engineering the interconnected arrays, the vision is potentially massive: one space-based solar array could include tens of millions of sheets and extend to sizes as large as a square mile – that’s more than three quarters the size of UToledo Main Campus. One array at this size could generate about 800 megawatts of electrical power – just shy of the power produced by the Davis Besse power plant between Toledo and Cleveland.

“”With 37% stronger sunlight above the atmosphere than on a typical sunny day here on Earth’s surface, orbital solar arrays offer a critical opportunity to harness renewable energy, achieve sustainability goals and provide strategic power for a wide range of orbital and airborne technologies,” said Dr. Randall Ellingson, professor in the UToledo Department of Physics and Astronomy and member of the UToledo Wright Center for Photovoltaics Innovation and Commercialization who will lead the five-year project.

“”This $12.5 million award recognizes our own University of Toledo as a national leader in solar cell technologies and in photovoltaic energy research,” said Congresswoman Marcy Kaptur. “UToledo’s broad partnerships with industry, government and academia represent the best of us and will help cement our region as a player for generations to come in solar manufacturing, research and development.”

Building on UToledo’s more than 30-year history advancing solar technology to power the world using clean energy, the physicists will continue developing the material science and photovoltaic technologies that are highly efficient, lightweight and durable in an outer-space environment.

They’re building tandem solar cells – two different solar cells stacked on top of each other that more efficiently harvest the sun’s spectrum – on very thin, flexible supporting materials.

“”We have had great success accelerating the performance of solar cells and drawing record levels of power from the same amount of sunlight using the tandem technique with what are called perovskites,” Ellingson said.

Perovskites are compound materials with a special crystal structure formed through chemistry.

The team will sandwich a variety of combinations of solar cells, including perovskites, silicon, cadmium telluride and copper indium gallium selenide, to raise the ceiling on what is achievable.

At the same time, the team will explore lightweight, flexible supporting material to create the large solar cell sheets. Those materials also need to be resilient, ultra-thin and tolerant to high and low temperatures. Semitransparent and very thin ceramic, plastics and glass are under consideration.

“Professor Ellingson and his team have demonstrated their ability to provide the Air Force with outstanding results over the years and the University is pleased that Representative Kaptur prioritizes projects that both advance the nation’s leadership in cutting-edge solar energy technology and provide the Department of Defense with the highest level of support from University research,” said Dr. Frank Calzonetti, UToledo vice president of research.

In 2019 the U.S. Air Force awarded Ellingson’s team $7.4 million to develop solar technology to power space vehicles using sunlight.

“”The Air Force has demanding specifications for its spaced-based power systems, and the advances being made in thin-film photovoltaics at UToledo coupled with our new photovoltaic sheets concept provide an avenue to meet them,” said Dr. Michael Heben, UToledo professor of physics and McMaster endowed chair. “The faculty and staff at UToledo’s Wright Center for Photovoltaics are proud to receive this award and excited about the challenge.”

In 2019 the U.S. Department of Energy awarded UToledo $4.5 million to develop the next-generation solar panel by bringing a new, ultra-high efficiency material to the consumer market. As part of the project, Dr. Yanfa Yan, UToledo professor of physics, is working with the National Renewable Energy Laboratory and First Solar to develop industrially relevant methods for both the fabrication and performance prediction of low-cost, efficient and stable perovskite thin-film PV modules.

Also in 2019 UToledo was part of a $3.9 million award led by Colorado State University to collaborate with the National Renewable Energy Laboratory, First Solar and the University of Illinois at Chicago on a U.S. Department of Energy-funded project to improve the voltage and power produced by cadmium-telluride-based solar cells.

UToledo’s Wright Center for Photovoltaics Innovation and Commercialization is a founding member of an organization called the U.S. Manufacturing of Advanced Perovskites Consortium, which is focused on moving a breakthrough new technology out of the lab and into the marketplace to enhance economic and national security. Partners include the U.S. Department of Energy’s National Renewable Energy Laboratory in Golden, Colo.; Washington Clean Energy Testbeds at the University of Washington; University of North Carolina at Chapel Hill; and six domestic companies that are working to commercialize the technology.

The University created the Wright Center for Photovoltaics Innovation and Commercialization in January 2007 with an $18.6 million award from the Ohio Department of Development in response to a proposal led by Dr. Robert Collins, Distinguished University Professor and NEG Endowed Chair of Silicate and Materials Science. Matching contributions of $30 million from federal agencies, universities and industrial partners helped to launch the center, which works to strengthen the photovoltaics and manufacturing base in Ohio through materials and design innovation.

“Solar electricity now competes economically with fossil-fueled and nuclear electricity while avoiding significant atmospheric carbon emissions which drive climate change,” Ellingson said.

“UToledo has assisted in driving down the cost of solar,” Heben said. “Over the past 15 years the cost of solar has been reduced by a factor of 10, while the amount of solar annually deployed has grown by a factor of 100, currently amounting to about 2% of the U.S. electricity supply. Importantly, the transition to clean solar electricity that is occurring also is creating tremendous new job growth opportunities in many parts of our economy.”

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Solar Energy

Breakthrough new material brings affordable, sustainable future within grasp

Published

5 hours ago

December 22, 2024

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Breakthrough new material brings affordable, sustainable future within grasp

by Rashda Khan for Canepa News

Houston TX (SPX) Dec 23, 2024

While lithium-ion batteries have been the go-to technology for everything from smartphones and laptops to electric cars, there are growing concerns about the future because lithium is relatively scarce, expensive and difficult to source, and may soon be at risk due to geopolitical considerations. Scientists around the world are working to create viable alternatives.

An international team of interdisciplinary researchers, including the Canepa Research Laboratory at the University of Houston, has developed a new type of material for sodium-ion batteries that could make them more efficient and boost their energy performance – paving the way for a more sustainable and affordable energy future.

The new material, sodium vanadium phosphate with the chemical formula NaxV2(PO4)3, improves sodium-ion battery performance by increasing the energy density – the amount of energy stored per kilogram – by more than 15%. With a higher energy density of 458 watt-hours per kilogram (Wh/kg) compared to the 396 Wh/kg in older sodium-ion batteries, this material brings sodium technology closer to competing with lithium-ion batteries.

“Sodium is nearly 50 times cheaper than lithium and can even be harvested from seawater, making it a much more sustainable option for large-scale energy storage,” said Pieremanuele Canepa, Robert Welch assistant professor of electrical and computer engineering at UH and lead researcher of the Canepa Lab. “Sodium-ion batteries could be cheaper and easier to produce, helping reduce reliance on lithium and making battery technology more accessible worldwide.”

From Theory to Reality

The Canepa Lab, which uses theoretical expertise and computational methods to discover new materials and molecules to help advance clean energy technologies, collaborated with the research groups headed by French researchers Christian Masquelier and Laurence Croguennec from the Laboratoire de Rea’ctivite’ et de Chimie des Solides, which is a CNRS laboratory part of the Universite’ de Picardie Jules Verne, in Amiens France, and the Institut de Chimie de la Matie`re Condense’e de Bordeaux, Universite’ de Bordeaux, Bordeaux, France for the experimental work on the project. This allowed theoretical modelling to go through experimental validation.

The researchers created a battery prototype using the new material, NaxV2(PO4)3, demonstrating significant energy storage improvements. NaxV2(PO4)3, part of a group called “Na superionic conductors” or NaSICONs, is designed to let sodium ions move smoothly in and out of the battery during charging and discharging.

Unlike existing materials, it has a unique way of handling sodium, allowing it to work as a single-phase system. This means it remains stable as it releases or takes in sodium ions. This allows the NaSICON to remain stable during charging and discharging while delivering a continuous voltage of 3.7 volts versus sodium metal, higher than the 3.37 volts in existing materials.

While this difference may seem small, it significantly increases the battery’s energy density or how much energy it can store for its weight. The key to its efficiency is vanadium, which can exist in multiple stable states, allowing it to hold and release more energy.

“The continuous voltage change is a key feature,” said Canepa. “It means the battery can perform more efficiently without compromising the electrode stability. That’s a game-changer for sodium-ion technology.”

Possibilities for a Sustainable Future

The implications of this work extend beyond sodium-ion batteries. The synthesis method used to create NaxV2(PO4)3 could be applied to other materials with similar chemistries, opening new possibilities for advanced energy storage technologies. That could in turn, impact everything from more affordable, sustainable batteries to power our devices to help us transition to a cleaner energy economy.

“Our goal is to find clean, sustainable solutions for energy storage,” Canepa said. “This material shows that sodium-ion batteries can meet the high-energy demands of modern technology while being cost-effective and environmentally friendly.”

A paper based on this work was published in the journal Nature Materials. Ziliang Wang, Canepa’s former student and now a postdoctoral fellow at Northwestern University, and Sunkyu Park, a former student of the French researchers and now a staff engineer at Samsung SDI in South Korea, performed much of the work on this project.

Research Report:Obtaining V2(PO4)3 by sodium extraction from single-phase NaxV2(PO4)3 (1 < x < 3) positive electrode materials

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Solar Energy

Pioneering advancements in solid-state battery technology for energy storage

Published

6 hours ago

December 22, 2024

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Pioneering advancements in solid-state battery technology for energy storage

by Riko Seibo

Tokyo, Japan (SPX) Dec 23, 2024

Recent strides in solid-state battery technology are setting the stage for a transformative era in energy storage. These advancements hold promise for revolutionizing electric vehicles and renewable energy systems through improved performance and safety. A focus on electrolyte innovation has been key to this progress, enabling the development of high-performance all-solid-state batteries (ASSBs).

A new review paper provides a comprehensive summary of advancements in inorganic solid electrolytes (ISEs), materials that are central to ASSBs. Researchers examined the roles of oxides, sulfides, hydroborates, antiperovskites, and halides not only as electrolytes but also as catholytes and interface layers, which collectively enhance battery performance and safety.

“We highlighted the recent breakthroughs in synthesizing these materials, honing our attention on the innovative techniques that enable the precise tuning of their properties to meet the demanding requirements of ASSBs,” said Eric Jianfeng Cheng, associate professor at Tohoku University’s Advanced Institute for Materials Research (AIMR). “Precise tuning is crucial for developing batteries with higher energy densities, longer life cycles, and better safety profiles than conventional liquid-based batteries.”

The review also delves into the electrochemical properties of ISEs, including ionic conductivity, stability, and electrode compatibility. Researchers evaluated current ASSB models and suggested emerging strategies that could drive the next generation of energy storage solutions.

However, challenges persist in the development of ASSBs, notably the limited compatibility between ISEs and electrodes, which can trigger interfacial reactions. Addressing these compatibility issues is vital to improving battery efficiency and longevity. The review outlines these challenges and provides insights into efforts aimed at overcoming them.

“Our comprehensive review underscores the importance of continued research and development in the field of solid-state batteries. By developing new materials, improving synthesis methods, and overcoming compatibility issues, current efforts are driving innovation toward practical ASSBs that could transform how we store and use energy,” Cheng added.

Research Report:Inorganic solid electrolytes for all-solid-state lithium/sodium-ion batteries: recent developments and applications

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Solar Energy

Buried interface engineering drives advances in tin-lead perovskite solar cell efficiency

Published

2 days ago

December 20, 2024

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Buried interface engineering drives advances in tin-lead perovskite solar cell efficiency

by Simon Mansfield

Sydney, Australia (SPX) Dec 20, 2024

A team led by Prof. Meng Li from Henan University’s School of Nanoscience and Materials Engineering has unveiled an innovative approach to overcoming stability and efficiency challenges in tin-lead (Sn-Pb) perovskite solar cells. The researchers’ work focuses on optimizing the buried hole-selective interface using a specially designed self-assembled material, offering major implications for single-junction and tandem solar cell technologies.

Tin-lead perovskites are valued for their narrow bandgap properties, which position them as key materials for producing high-efficiency solar cells. However, energy level mismatches and degradation at the buried interface have constrained both their performance and long-term stability. Addressing these issues, Prof. Meng’s team designed a boronic acid-anchored hole-selective contact material, 4-(9H-carbazole-9-yl)phenylboronic acid (4PBA).

Compared to conventional materials, 4PBA demonstrated superior stability and compatibility at the substrate surface. Its high adsorption energy of -5.24 eV and significant molecular dipole moment (4.524 D) improved energy level alignment between the substrate and perovskite layer, facilitating efficient charge extraction. Additionally, the interface engineered using 4PBA improved perovskite crystallization and substrate contact, reducing defects and non-radiative recombination.

These advancements enabled Sn-Pb perovskite solar cells incorporating 4PBA to achieve a power conversion efficiency (PCE) of 23.45%. The material’s reduced corrosiveness also mitigated the degradation effects typically caused by PEDOT:PSS, a widely used hole-transport material, enhancing chemical stability and storage durability. The cells retained 93.5% of their initial efficiency after 2,000 hours of shelf storage.

“This approach offers a practical path to enhancing both the efficiency and stability of Sn-Pb perovskite solar cells, addressing energy level mismatches and interfacial stability concerns,” the research team commented.

The findings provide a foundation for advancing efficient and stable Sn-Pb perovskite solar cells and highlight the importance of interface engineering in next-generation photovoltaic technologies.

Research Report:Buried Hole-Selective Interface Engineering for High-Efficiency Tin-Lead Perovskite Solar Cells with Enhanced Interfacial Chemical Stability