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Discovery changes understanding of water’s history on the Moon
New research from a Western University postdoctoral fellow shows the early lunar crust which makes up the surface of the Moon was considerably enriched in water more than 4 billion years ago, counter to previously held understanding. The discovery is outlined in a study published today in the journal Nature Astronomy.
The research offers exciting new evidence that the Moon’s early crust contained more water than was originally thought, opening new doors into the study of lunar history.
“The discovery of apatite in the Moon’s early crust for the first time is incredibly exciting — as we can finally start to piece together this unknown stage of lunar history. We find the Moon’s early crust was richer in water than we expected, and its volatile stable isotopes reveal an even more complex history than we knew before,” said Hayden, currently working as a cosmochemist with planetary geologist Gordon “Oz” Osinski in Western’s department of Earth sciences.
“Lunar meteorites are revealing new, exciting parts of the Moon’s evolution and expanding our knowledge beyond the samples collected during the Apollo missions. As the new stage of lunar exploration begins, I am eager to see what we will learn from the lunar far side,” said Hayden.
The Apollo samples were first assumed to be ‘volatile-poor’ upon their return from the Moon, leading to the wide-known description of the Moon as ‘bone dry.’
In 2008, Alberto Saal and other researchers discovered the presence of significant amounts of water and other volatiles in glass beads from the Apollo sample collection. This set forth fifteen years of re-analysis of the Apollo samples while newly found lunar meteorites have revealed the Moon had much more water across its surface.
“We know most about the history of water on the Moon from the Apollo samples, but those samples are thought to only represent about five per cent of the entire Moon surface,” said Hayden. “Until we get more samples back in the upcoming Artemis missions, the only other samples from the surface we have are meteorites.”
Hayden made the discovery at The Open University during her PhD studies while verifying a rock sample for a collector as a lunar meteorite. Beyond its identification, the sample proved to be holding a key piece of data about water on the Moon.
“I was so lucky the meteorite not only came from the Moon but remarkably, featured chemistry so vital to our understanding about lunar water-bearing minerals,” said Hayden.
This work was focused primarily on the mineral apatite, which contains volatile elements in its mineral structure. Apatite was found in all lunar rock types except glass beads and ferroan anorthosites, the latter representing the Moon’s early crust. The Ferroan Anorthosite group is known to be incredibly old (4.5-4.3 billion years old) and is the only rock type known to have formed directly from the Lunar Magma Ocean — when the Moon was almost entirely molten.
The discovery of apatite in this rock type has allowed for the direct examination of this unknown stage in lunar evolution for the first time.
“Unravelling the history of water in the earliest-formed lunar crust approximately 4.5 billion years ago is important for improving our understanding of the origin of water in the Solar System. Ancient rock samples from the Moon in the form of lunar meteorites provide an excellent opportunity for undertaking such investigations,” said Mahesh Anand, professor of planetary science and exploration at The Open University and Hayden’s formal lead supervisor.
Future Artemis missions
Hayden says the timing of the discovery is perfect as the NASA Artemis missions are preparing for launch and researchers, including her current supervisor, are developing programing and targets for the astronauts.
“It has been long believed the lunar surface has been dried out for thousands and even millions of years, but maybe there might be more water available than we thought on the surface of the Moon and we just need to find a way to extract it,” said Hayden.
Osinski is equally excited for the potential opportunities of this new discovery.
Last year, Osinski was selected for the NASA geology team that is developing the surface science plan for the first crewed lunar landing mission in more than 50 years. He will join his colleagues in mission control’s science backroom at NASA’s Johnson Space Center in Houston providing support throughout the Artemis III mission.
“Tara’s discoveries are super exciting and will feed into our sampling strategy for the Artemis III mission where we hope to identify and sample some of the earliest crust on the Moon,” said Osinski.
Osinski also serves as principal investigator and scientific lead on Canada’s first lunar rover, which is being designed and built by Canadensys Aerospace.
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Early dark energy could resolve cosmology’s two biggest puzzles
A new study by MIT physicists proposes that a mysterious force known as early dark energy could solve two of the biggest puzzles in cosmology and fill in some major gaps in our understanding of how the early universe evolved.
Now, the MIT team has found that both puzzles could be resolved if the early universe had one extra, fleeting ingredient: early dark energy. Dark energy is an unknown form of energy that physicists suspect is driving the expansion of the universe today. Early dark energy is a similar, hypothetical phenomenon that may have made only a brief appearance, influencing the expansion of the universe in its first moments before disappearing entirely.
Some physicists have suspected that early dark energy could be the key to solving the Hubble tension, as the mysterious force could accelerate the early expansion of the universe by an amount that would resolve the measurement mismatch.
The MIT researchers have now found that early dark energy could also explain the baffling number of bright galaxies that astronomers have observed in the early universe. In their new study, reported in the Monthly Notices of the Royal Astronomical Society, the team modeled the formation of galaxies in the universe’s first few hundred million years. When they incorporated a dark energy component only in that earliest sliver of time, they found the number of galaxies that arose from the primordial environment bloomed to fit astronomers’ observations.
“You have these two looming open-ended puzzles,” says study co-author Rohan Naidu, a postdoc in MIT’s Kavli Institute for Astrophysics and Space Research. “We find that in fact, early dark energy is a very elegant and sparse solution to two of the most pressing problems in cosmology.”
The study’s co-authors include lead author and Kavli postdoc Xuejian (Jacob) Shen, and MIT professor of physics Mark Vogelsberger, along with Michael Boylan-Kolchin at the University of Texas at Austin, and Sandro Tacchella at the University of Cambridge.
Big city lights
Based on standard cosmological and galaxy formation models, the universe should have taken its time spinning up the first galaxies. It would have taken billions of years for primordial gas to coalesce into galaxies as large and bright as the Milky Way.
But in 2023, NASA’s James Webb Space Telescope (JWST) made a startling observation. With an ability to peer farther back in time than any observatory to date, the telescope uncovered a surprising number of bright galaxies as large as the modern Milky Way within the first 500 million years, when the universe was just 3 percent of its current age.
“The bright galaxies that JWST saw would be like seeing a clustering of lights around big cities, whereas theory predicts something like the light around more rural settings like Yellowstone National Park,” Shen says. “And we don’t expect that clustering of light so early on.”
For physicists, the observations imply that there is either something fundamentally wrong with the physics underlying the models or a missing ingredient in the early universe that scientists have not accounted for. The MIT team explored the possibility of the latter, and whether the missing ingredient might be early dark energy.
Physicists have proposed that early dark energy is a sort of antigravitational force that is turned on only at very early times. This force would counteract gravity’s inward pull and accelerate the early expansion of the universe, in a way that would resolve the mismatch in measurements. Early dark energy, therefore, is considered the most likely solution to the Hubble tension.
Galaxy skeleton
The MIT team explored whether early dark energy could also be the key to explaining the unexpected population of large, bright galaxies detected by JWST. In their new study, the physicists considered how early dark energy might affect the early structure of the universe that gave rise to the first galaxies. They focused on the formation of dark matter halos — regions of space where gravity happens to be stronger, and where matter begins to accumulate.
“We believe that dark matter halos are the invisible skeleton of the universe,” Shen explains. “Dark matter structures form first, and then galaxies form within these structures. So, we expect the number of bright galaxies should be proportional to the number of big dark matter halos.”
The team developed an empirical framework for early galaxy formation, which predicts the number, luminosity, and size of galaxies that should form in the early universe, given some measures of “cosmological parameters.” Cosmological parameters are the basic ingredients, or mathematical terms, that describe the evolution of the universe.
Physicists have determined that there are at least six main cosmological parameters, one of which is the Hubble constant — a term that describes the universe’s rate of expansion. Other parameters describe density fluctuations in the primordial soup, immediately after the Big Bang, from which dark matter halos eventually form.
The MIT team reasoned that if early dark energy affects the universe’s early expansion rate, in a way that resolves the Hubble tension, then it could affect the balance of the other cosmological parameters, in a way that might increase the number of bright galaxies that appear at early times. To test their theory, they incorporated a model of early dark energy (the same one that happens to resolve the Hubble tension) into an empirical galaxy formation framework to see how the earliest dark matter structures evolve and give rise to the first galaxies.
“What we show is, the skeletal structure of the early universe is altered in a subtle way where the amplitude of fluctuations goes up, and you get bigger halos, and brighter galaxies that are in place at earlier times, more so than in our more vanilla models,” Naidu says. “It means things were more abundant, and more clustered in the early universe.”
“A priori, I would not have expected the abundance of JWST’s early bright galaxies to have anything to do with early dark energy, but their observation that EDE pushes cosmological parameters in a direction that boosts the early-galaxy abundance is interesting,” says Marc Kamionkowski, professor of theoretical physics at Johns Hopkins University, who was not involved with the study. “I think more work will need to be done to establish a link between early galaxies and EDE, but regardless of how things turn out, it’s a clever — and hopefully ultimately fruitful — thing to try.”
“We demonstrated the potential of early dark energy as a unified solution to the two major issues faced by cosmology. This might be an evidence for its existence if the observational findings of JWST get further consolidated,” Vogelsberger concludes. “In the future, we can incorporate this into large cosmological simulations to see what detailed predictions we get.”
This research was supported, in part, by NASA and the National Science Foundation.
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Plant-derived secondary organic aerosols can act as mediators of plant-plant interactions
A new study published in Science reveals that plant-derived secondary organic aerosols (SOAs) can act as mediators of plant-plant interactions. This research was conducted through the cooperation of chemical ecologists, plant ecophysiologists and atmospheric physicists at the University of Eastern Finland.
The study showed that Scots pine seedlings, when damaged by large pine weevils, release VOCs that activate defences in nearby plants of the same species. Interestingly, the biological activity persisted after VOCs were oxidized to form SOAs. The results indicated that the elemental composition and quantity of SOAs likely determines their biological functions.
“A key novelty of the study is the finding that plants adopt subtly different defence strategies when receiving signals as VOCs or as SOAs, yet they exhibit similar degrees of resistance to herbivore feeding,” said Professor James Blande, head of the Environmental Ecology Research Group. This observation opens up the possibility that plants have sophisticated sensing systems that enable them to tailor their defences to information derived from different types of chemical cue.
“Considering the formation rate of SOAs from their precursor VOCs, their longer lifetime compared to VOCs, and the atmospheric air mass transport, we expect that the ecologically effective distance for interactions mediated by SOAs is longer than that for plant interactions mediated by VOCs,” said Professor Annele Virtanen, head of the Aerosol Physics Research Group. This could be interpreted as plants being able to detect cues representing close versus distant threats from herbivores.
The study is expected to open up a whole new complex research area to environmental ecologists and their collaborators, which could lead to new insights on the chemical cues structuring interactions between plants.
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Folded or cut, this lithium-sulfur battery keeps going
Most rechargeable batteries that power portable devices, such as toys, handheld vacuums and e-bikes, use lithium-ion technology. But these batteries can have short lifetimes and may catch fire when damaged. To address stability and safety issues, researchers reporting in ACS Energy Letters have designed a lithium-sulfur (Li-S) battery that features an improved iron sulfide cathode. One prototype remains highly stable over 300 charge-discharge cycles, and another provides power even after being folded or cut.
The team coated iron sulfide cathodes in different polymers and found in initial electrochemical performance tests that polyacrylic acid (PAA) performed best, retaining the electrode’s discharge capacity after 300 charge-discharge cycles. Next, the researchers incorporated a PAA-coated iron sulfide cathode into a prototype battery design, which also included a carbonate-based electrolyte, a lithium metal foil as an ion source, and a graphite-based anode. They produced and then tested both pouch cell and coin cell battery prototypes.
After more than 100 charge-discharge cycles, Wang and colleagues observed no substantial capacity decay in the pouch cell. Additional experiments showed that the pouch cell still worked after being folded and cut in half. The coin cell retained 72% of its capacity after 300 charge-discharge cycles. They next applied the polymer coating to cathodes made from other metals, creating lithium-molybdenum and lithium-vanadium batteries. These cells also had stable capacity over 300 charge-discharge cycles. Overall, the results indicate that coated cathodes could produce not only safer Li-S batteries with long lifespans, but also efficient batteries with other metal sulfides, according to Wang’s team.
The authors acknowledge funding from the National Natural Science Foundation of China; the Natural Science Foundation of Sichuan, China; and the Beijing National Laboratory for Condensed Matter Physics.
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