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Neptune-like exoplanets can be cloudy or clear

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Neptune-like exoplanets can be cloudy or clear


The study of “exoplanets,” the sci-fi-sounding name for all planets in the cosmos beyond our own solar system, is a pretty new field. Mainly, exoplanet researchers like those in the ExoLab at the University of Kansas use data from space-borne telescopes such as the Hubble Space Telescope and Webb Space Telescope. Whenever news headlines offer findings of “Earth-like” planets or planets with the potential to support humanity, they’re talking about exoplanets within our own Milky Way.

Jonathan Brande, a doctoral candidate in the ExoLab at the University of Kansas, has just published findings in the open-access scientific journal The Astrophysical Journal Letters showing new atmospheric detail in a set of 15 exoplanets similar to Neptune. While none could support humanity, a better understanding of their behavior might help us to understand why we don’t have a small Neptune, while most solar systems seem to feature a planet of this class.

“Over the past several years at KU, my focus has been studying the atmospheres of exoplanets through a technique known as transmission spectroscopy,” Brande said. “When a planet transits, meaning it moves between our line of sight and the star it orbits, light from the star passes through the planet’s atmosphere, getting absorbed by the various gases present. By capturing a spectrum of the star — passing the light through an instrument called a spectrograph, akin to passing it through a prism — we observe a rainbow, measuring the brightness of different constituent colors. Varied areas of brightness or dimness in the spectrum reveal the gases absorbing light in the planet’s atmosphere.”

With this methodology, several years ago Brande published a paper concerning the “warm Neptune” exoplanet TOI-674 b, where he presented observations indicating the presence of water vapor in its atmosphere. These observations were part of a broader program led by Brande’s adviser, Ian Crossfield, associate professor of physics & astronomy at KU, to observe atmospheres of Neptune-sized exoplanets.

“We want to comprehend the behaviors of these planets, given that those slightly larger than Earth and smaller than Neptune are the most common in the galaxy,” Brande said.

This recent ApJL paper summarizes observations from that program, incorporating data from additional observations to address why some planets appear cloudy while others are clear.

“The goal is to explore the physical explanations behind the distinct appearances of these planets,” Brande said.

Brande and his co-authors took special note of regions where exoplanets tend to form clouds or hazes high up in their atmosphere. When such atmospheric aerosols are present, the KU researcher said hazes can block the light filtering through the atmosphere.

“If a planet has a cloud right above the surface with hundreds of kilometers of clear air above it, starlight can easily pass through the clear air and be absorbed only by the specific gases in that part of the atmosphere,” Brande said. “However, if the cloud is positioned very high, clouds are generally opaque across the electromagnetic spectrum. While hazes have spectral features, for our work, where we focus on a relatively narrow range with Hubble, they also produce mostly flat spectra.”

According to Brande, when these aerosols are present high in the atmosphere, there’s no clear path for light to filter through.

“With Hubble, the single gas we’re most sensitive to is water vapor,” he said. “If we observe water vapor in a planet’s atmosphere, that’s a good indication that there are no clouds high enough to block its absorption. Conversely, if water vapor is not observed and only a flat spectrum is seen, despite knowing that the planet should have an extended atmosphere, it suggests the likely presence of clouds or hazes at higher altitudes.”

Brande led the work of an international team of astronomers on the paper, including Crossfield at KU and collaborators from the Max Planck Institute in Heidelberg, Germany, a cohort led by Laura Kreidberg, and investigators at the University of Texas, Austin, led by Caroline Morley.

Brande and his co-authors approached their analysis differently than previous efforts by focusing on determining the physical parameters of the small-Neptune atmospheres. In contrast, previous analyses often involved fitting a single model spectrum to observations.

“Typically, researchers would take an atmospheric model with pre-computed water content, scale and shift it to match observed planets in their sample,” Brande said. “This approach indicates whether the spectrum is clear or cloudy but provides no information about the amount of water vapor or the location of clouds in the atmosphere.”

Instead, Brande employed a technique known as “atmospheric retrieval.”

“This involved modeling the atmosphere across various planet parameters such as water vapor quantity and cloud location, iterating through hundreds and thousands of simulations to find the best fit configuration,” he said. “Our retrievals gave us a best-fit model spectrum for each planet, from which we calculated how cloudy or clear the planet appeared to be. Then, we compared those measured clarities to a separate suite of models by Caroline Morley, which let us see that our results are in line with expectations for similar planets. In examining cloud and haze behavior, our models indicated that clouds were a better fit than hazes. The sedimentation efficiency parameter, reflecting cloud compactness, suggested observed planets had relatively low sedimentation efficiencies, resulting in fluffy clouds. These clouds, made up of particles like water droplets, remained lofted in the atmosphere due to their low settling tendency.”

Brande’s findings provide insights into the behavior of these planetary atmospheres and caused “substantial interest” when he presented them at a recent meeting of the American Astronomical Society.

Other findings

Moreover, Brande is part of an international observation program, led by Crossfield, that just announced findings of water vapor on GJ 9827d — a planet as hot as Venus 97 light-years from Earth in the constellation Pisces.

The observations, made with the Hubble Space Telescope, show the planet may be just one example of water-rich planets in the Milky Way. They were announced by a team led by Pierre-Alexis Roy of the Trottier Institute for Research on Exoplanets at Université de Montréal.

“We were searching for water vapor on the atmospheres of sub-Neptune-type planets,” Brande said. “Pierre-Alexis’ paper is the latest from that main effort because it took approximately 10 or 11 orbits or transits of the planet to make the water-vapor detection. Pierre-Alexis’ spectrum made it into our paper as one of our trend-data points, and we included all the planets from their proposal and others studied in the literature, making our results stronger. We were in close communication with them during the process of both papers to ensure we were using the proper updated results and accurately reflecting their findings.”



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Early dark energy could resolve cosmology’s two biggest puzzles

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A new study by MIT physicists proposes that a mysterious force known as early dark energy could solve two of the biggest puzzles in cosmology and fill in some major gaps in our understanding of how the early universe evolved.

One puzzle in question is the “Hubble tension,” which refers to a mismatch in measurements of how fast the universe is expanding. The other involves observations of numerous early, bright galaxies that existed at a time when the early universe should have been much less populated.

Now, the MIT team has found that both puzzles could be resolved if the early universe had one extra, fleeting ingredient: early dark energy. Dark energy is an unknown form of energy that physicists suspect is driving the expansion of the universe today. Early dark energy is a similar, hypothetical phenomenon that may have made only a brief appearance, influencing the expansion of the universe in its first moments before disappearing entirely.

Some physicists have suspected that early dark energy could be the key to solving the Hubble tension, as the mysterious force could accelerate the early expansion of the universe by an amount that would resolve the measurement mismatch.

The MIT researchers have now found that early dark energy could also explain the baffling number of bright galaxies that astronomers have observed in the early universe. In their new study, reported in the Monthly Notices of the Royal Astronomical Society, the team modeled the formation of galaxies in the universe’s first few hundred million years. When they incorporated a dark energy component only in that earliest sliver of time, they found the number of galaxies that arose from the primordial environment bloomed to fit astronomers’ observations.

You have these two looming open-ended puzzles,” says study co-author Rohan Naidu, a postdoc in MIT’s Kavli Institute for Astrophysics and Space Research. “We find that in fact, early dark energy is a very elegant and sparse solution to two of the most pressing problems in cosmology.”

The study’s co-authors include lead author and Kavli postdoc Xuejian (Jacob) Shen, and MIT professor of physics Mark Vogelsberger, along with Michael Boylan-Kolchin at the University of Texas at Austin, and Sandro Tacchella at the University of Cambridge.

Big city lights

Based on standard cosmological and galaxy formation models, the universe should have taken its time spinning up the first galaxies. It would have taken billions of years for primordial gas to coalesce into galaxies as large and bright as the Milky Way.

But in 2023, NASA’s James Webb Space Telescope (JWST) made a startling observation. With an ability to peer farther back in time than any observatory to date, the telescope uncovered a surprising number of bright galaxies as large as the modern Milky Way within the first 500 million years, when the universe was just 3 percent of its current age.

“The bright galaxies that JWST saw would be like seeing a clustering of lights around big cities, whereas theory predicts something like the light around more rural settings like Yellowstone National Park,” Shen says. “And we don’t expect that clustering of light so early on.”

For physicists, the observations imply that there is either something fundamentally wrong with the physics underlying the models or a missing ingredient in the early universe that scientists have not accounted for. The MIT team explored the possibility of the latter, and whether the missing ingredient might be early dark energy.

Physicists have proposed that early dark energy is a sort of antigravitational force that is turned on only at very early times. This force would counteract gravity’s inward pull and accelerate the early expansion of the universe, in a way that would resolve the mismatch in measurements. Early dark energy, therefore, is considered the most likely solution to the Hubble tension.

Galaxy skeleton

The MIT team explored whether early dark energy could also be the key to explaining the unexpected population of large, bright galaxies detected by JWST. In their new study, the physicists considered how early dark energy might affect the early structure of the universe that gave rise to the first galaxies. They focused on the formation of dark matter halos — regions of space where gravity happens to be stronger, and where matter begins to accumulate.

“We believe that dark matter halos are the invisible skeleton of the universe,” Shen explains. “Dark matter structures form first, and then galaxies form within these structures. So, we expect the number of bright galaxies should be proportional to the number of big dark matter halos.”

The team developed an empirical framework for early galaxy formation, which predicts the number, luminosity, and size of galaxies that should form in the early universe, given some measures of “cosmological parameters.” Cosmological parameters are the basic ingredients, or mathematical terms, that describe the evolution of the universe.

Physicists have determined that there are at least six main cosmological parameters, one of which is the Hubble constant — a term that describes the universe’s rate of expansion. Other parameters describe density fluctuations in the primordial soup, immediately after the Big Bang, from which dark matter halos eventually form.

The MIT team reasoned that if early dark energy affects the universe’s early expansion rate, in a way that resolves the Hubble tension, then it could affect the balance of the other cosmological parameters, in a way that might increase the number of bright galaxies that appear at early times. To test their theory, they incorporated a model of early dark energy (the same one that happens to resolve the Hubble tension) into an empirical galaxy formation framework to see how the earliest dark matter structures evolve and give rise to the first galaxies.

“What we show is, the skeletal structure of the early universe is altered in a subtle way where the amplitude of fluctuations goes up, and you get bigger halos, and brighter galaxies that are in place at earlier times, more so than in our more vanilla models,” Naidu says. “It means things were more abundant, and more clustered in the early universe.”

“A priori, I would not have expected the abundance of JWST’s early bright galaxies to have anything to do with early dark energy, but their observation that EDE pushes cosmological parameters in a direction that boosts the early-galaxy abundance is interesting,” says Marc Kamionkowski, professor of theoretical physics at Johns Hopkins University, who was not involved with the study. “I think more work will need to be done to establish a link between early galaxies and EDE, but regardless of how things turn out, it’s a clever — and hopefully ultimately fruitful — thing to try.”

We demonstrated the potential of early dark energy as a unified solution to the two major issues faced by cosmology. This might be an evidence for its existence if the observational findings of JWST get further consolidated,” Vogelsberger concludes. “In the future, we can incorporate this into large cosmological simulations to see what detailed predictions we get.”

This research was supported, in part, by NASA and the National Science Foundation.



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Plant-derived secondary organic aerosols can act as mediators of plant-plant interactions

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A new study published in Science reveals that plant-derived secondary organic aerosols (SOAs) can act as mediators of plant-plant interactions. This research was conducted through the cooperation of chemical ecologists, plant ecophysiologists and atmospheric physicists at the University of Eastern Finland.

It is well known that plants release volatile organic compounds (VOCs) into the atmosphere when damaged by herbivores. These VOCs play a crucial role in plant-plant interactions, whereby undamaged plants may detect warning signals from their damaged neighbours and prepare their defences. “Reactive plant VOCs undergo oxidative chemical reactions, resulting in the formation of secondary organic aerosols (SOAs). We wondered whether the ecological functions mediated by VOCs persist after they are oxidated to form SOAs,” said Dr. Hao Yu, formerly a PhD student at UEF, but now at the University of Bern.

The study showed that Scots pine seedlings, when damaged by large pine weevils, release VOCs that activate defences in nearby plants of the same species. Interestingly, the biological activity persisted after VOCs were oxidized to form SOAs. The results indicated that the elemental composition and quantity of SOAs likely determines their biological functions.

“A key novelty of the study is the finding that plants adopt subtly different defence strategies when receiving signals as VOCs or as SOAs, yet they exhibit similar degrees of resistance to herbivore feeding,” said Professor James Blande, head of the Environmental Ecology Research Group. This observation opens up the possibility that plants have sophisticated sensing systems that enable them to tailor their defences to information derived from different types of chemical cue.

“Considering the formation rate of SOAs from their precursor VOCs, their longer lifetime compared to VOCs, and the atmospheric air mass transport, we expect that the ecologically effective distance for interactions mediated by SOAs is longer than that for plant interactions mediated by VOCs,” said Professor Annele Virtanen, head of the Aerosol Physics Research Group. This could be interpreted as plants being able to detect cues representing close versus distant threats from herbivores.

The study is expected to open up a whole new complex research area to environmental ecologists and their collaborators, which could lead to new insights on the chemical cues structuring interactions between plants.



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Folded or cut, this lithium-sulfur battery keeps going

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Most rechargeable batteries that power portable devices, such as toys, handheld vacuums and e-bikes, use lithium-ion technology. But these batteries can have short lifetimes and may catch fire when damaged. To address stability and safety issues, researchers reporting in ACS Energy Letters have designed a lithium-sulfur (Li-S) battery that features an improved iron sulfide cathode. One prototype remains highly stable over 300 charge-discharge cycles, and another provides power even after being folded or cut.

Sulfur has been suggested as a material for lithium-ion batteries because of its low cost and potential to hold more energy than lithium-metal oxides and other materials used in traditional ion-based versions. To make Li-S batteries stable at high temperatures, researchers have previously proposed using a carbonate-based electrolyte to separate the two electrodes (an iron sulfide cathode and a lithium metal-containing anode). However, as the sulfide in the cathode dissolves into the electrolyte, it forms an impenetrable precipitate, causing the cell to quickly lose capacity. Liping Wang and colleagues wondered if they could add a layer between the cathode and electrolyte to reduce this corrosion without reducing functionality and rechargeability.

The team coated iron sulfide cathodes in different polymers and found in initial electrochemical performance tests that polyacrylic acid (PAA) performed best, retaining the electrode’s discharge capacity after 300 charge-discharge cycles. Next, the researchers incorporated a PAA-coated iron sulfide cathode into a prototype battery design, which also included a carbonate-based electrolyte, a lithium metal foil as an ion source, and a graphite-based anode. They produced and then tested both pouch cell and coin cell battery prototypes.

After more than 100 charge-discharge cycles, Wang and colleagues observed no substantial capacity decay in the pouch cell. Additional experiments showed that the pouch cell still worked after being folded and cut in half. The coin cell retained 72% of its capacity after 300 charge-discharge cycles. They next applied the polymer coating to cathodes made from other metals, creating lithium-molybdenum and lithium-vanadium batteries. These cells also had stable capacity over 300 charge-discharge cycles. Overall, the results indicate that coated cathodes could produce not only safer Li-S batteries with long lifespans, but also efficient batteries with other metal sulfides, according to Wang’s team.

The authors acknowledge funding from the National Natural Science Foundation of China; the Natural Science Foundation of Sichuan, China; and the Beijing National Laboratory for Condensed Matter Physics.



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